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Diffusivities of Gases in Room-Temperature Ionic Liquids: Data and Correlations Obtained Using a Lag-Time Technique
Abstract
Diffusivity and solubility data are presented for carbon dioxide, ethylene, propylene, 1-butene, and 1,3-butadiene in five imidazolium-based ionic liquids and one phosphonium-based ionic liquid covering a liquid viscosity range of 10−1000 cP. The data were obtained using a lag-time technique that involves analysis of both the transient and steady-state permeation regimes through a supported liquid film. In general, gas diffusion in ionic liquids (∼10 -6 cm 2 /sec) is slower than that in traditional hydrocarbon solvents and water, but the dependence on viscosity is lower. Conversely, the dependence of diffusivity on temperature and the size of the solute gas is higher than that for nonpolar solvents. A correlation for gas diffusivity in ionic liquids at 30 °C is proposed in terms of the gas molar volume, the ionic liquid viscosity, and density, based on 30 data points with a coefficient of multiple determination r 2 = 0.975.
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Cites
Influence of chloride, water, and organic solvents on the physical properties of ionic liquids
Seddon, K. R., Stark, A., & Torres, M.-J. (2000) · Pure and Applied Chemistry · doi:10.1351/pac200072122275 · Cited by 2,293
Cited by
An overview of CO2 capture technologies
MacDowell, N., Florin, N., Buchard, A., Hallett, J., Galindo, A., Jackson, G., Adjiman, C. S., Williams, C. K., Shah, N., & Fennell, P. (2010) · Energy & Environmental Science · doi:10.1039/c004106h · Cited by 1,636
State-of-the-Art of CO2Capture with Ionic Liquids
Ramdin, M., de Loos, T. W., & Vlugt, T. J. H. (2012) · Industrial & Engineering Chemistry Research · doi:10.1021/ie3003705 · Cited by 1,073
Jessop, P. G., & Subramaniam, B. (2007) · Chemical Reviews · doi:10.1021/cr040199o · Cited by 561
Jin, H., Baker, G. A., Arzhantsev, S., Dong, J., & Maroncelli, M. (2007) · The Journal of Physical Chemistry B · doi:10.1021/jp070923h · Cited by 310
Gardas, R. L., & Coutinho, J. A. P. (2009) · AIChE Journal · doi:10.1002/aic.11737 · Cited by 305
Metadata
- Authors
- Morgan, D., Ferguson, L., & Scovazzo, P.
- Venue
- Industrial & Engineering Chemistry Research
- Publisher
- American Chemical Society (ACS)
- Published
- 2005-05-24
- Volume
- 44
- Issue
- 13
- Pages
- 4815-4823
- ISSN
- 0888-5885 (ISSN-L)
- 1520-5045
- OpenAlex
- W1966781307
- Cited by
- 369
- References
- 1
- FWCI
- 6.05
- Type
- journal article
- Language
- en
- Open access
- closed
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