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Selective Hydrogenolysis of Glycerol with Raney Nickel
Open accessAbstract
Glycerol, a cheap renewable feedstock, was converted selectively to 1,2-propanediol by heating under low hydrogen pressure (10 bar), in the presence of Raney nickel. No solvents or additives were required, and the product could be distilled out of the reaction mixture. Addition of a phosphonium salt, a liquid at the reaction temperature, improved the selectivity and rate to a small extent but did not facilitate the separation of the final reaction mixture.
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Citations
Cited by
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Corma, A., Iborra, S., & Velty, A. (2007) · Chemical Reviews · doi:10.1021/cr050989d · Cited by 5,970
Bozell, J. J., & Petersen, G. R. (2010) · Green Chemistry · doi:10.1039/b922014c · Cited by 4,566
Heterogeneous catalysis of the glycerol hydrogenolysis
Nakagawa, Y., & Tomishige, K. (2011) · Catalysis Science & Technology · doi:10.1039/c0cy00054j · Cited by 411
Huang, Z., Cui, F., Kang, H., Chen, J., Zhang, X., & Xia, C. (2008) · Chemistry of Materials · doi:10.1021/cm8006233 · Cited by 362
Nickel recovery/removal from industrial wastes: A review
Coman, V., Robotin, B., & Ilea, P. (2013) · Resources, Conservation and Recycling · doi:10.1016/j.resconrec.2013.01.019 · Cited by 324
Metadata
- Authors
- Perosa, A., & Tundo, P.
- Venue
- Industrial & Engineering Chemistry Research
- Publisher
- American Chemical Society (ACS)
- Published
- 2005-03-10
- Volume
- 44
- Issue
- 23
- Pages
- 8535-8537
- ISSN
- 0888-5885 (ISSN-L)
- 1520-5045
- OpenAlex
- W2001521590
- Cited by
- 216
- References
- 0
- FWCI
- 4.58
- Type
- journal article
- Language
- en
- Open access
- green
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- Perosa, A., & Tundo, P. (2005). Selective Hydrogenolysis of Glycerol with Raney Nickel. Industrial & Engineering Chemistry Research. https://doi.org/10.1021/ie0489251
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