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Bulk-Fluid Solubility and Membrane Feasibility of Rmim-Based Room-Temperature Ionic Liquids
Abstract
This paper shows how gas solubility can be predicted in Rmim-based room-temperature ionic liquids (RTILs). We have developed a model to illustrate that ideal, single-gas solubility in Rmim-based RTILs is primarily a function of molar volume of the RTIL. This method is used to estimate bulk-fluid gas solubility, showing that for Rmim-based RTILs there is a particular molar volume where a maximum amount of gas per volume of RTIL occurs at a given pressure and temperature. This method is also used to estimate gas permeability and gas pair separation selectivity for ideal CO 2 /N 2 and CO 2 /CH 4 separations. A comparison to traditional polymer membranes utilized in these separations is included in the form of a “Robeson plot”.
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Cited by
Room-Temperature Ionic Liquids and Composite Materials: Platform Technologies for CO2 Capture
Bara, J. E., Camper, D. E., Gin, D. L., & Noble, R. D. (2010) · Accounts of Chemical Research · doi:10.1021/ar9001747 · Cited by 623
Self-citationCO2 Capture from Dilute Gases as a Component of Modern Global Carbon Management
Jones, C. W. (2011) · Annual Review of Chemical and Biomolecular Engineering · doi:10.1146/annurev-chembioeng-061010-114252 · Cited by 268
Metadata
- Authors
- Camper, D., Bara, J., Koval, C., & Noble, R.
- Venue
- Industrial & Engineering Chemistry Research
- Publisher
- American Chemical Society (ACS)
- Published
- 2006-08-01
- Volume
- 45
- Issue
- 18
- Pages
- 6279-6283
- ISSN
- 0888-5885 (ISSN-L)
- 1520-5045
- OpenAlex
- W1993752575
- Cited by
- 248
- References
- 0
- FWCI
- 2.93
- Type
- journal article
- Language
- en
- Open access
- closed
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- Camper, D., Bara, J., Koval, C., & Noble, R. (2006). Bulk-Fluid Solubility and Membrane Feasibility of Rmim-Based Room-Temperature Ionic Liquids. Industrial & Engineering Chemistry Research. https://doi.org/10.1021/ie060177n
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