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Flame Retardancy and Thermal Degradation of Intumescent Flame Retardant Poly(lactic acid)/Starch Biocomposites

Wang, Xin, Hu, Yuan, Song, Lei, Xuan, Shanyong, Xing, Weiyi, Bai, Zhiman, Lu, Hongdian·2011·Industrial & Engineering Chemistry Research

Abstract

Intumescent flame-retardant poly(lactic acid)/starch (PLA/starch) biocomposites were prepared by means of melt blending. Microencapsulated ammonium polyphosphate (MCAPP) was added to the PLA/starch biocomposites not only to improve its flame retardancy but also to restrain the reaction between ammonium polyphosphate and starch during processing. The flame-retardant properties of PLA/starch biocomposites were evaluated by limiting oxygen index, UL-94 test, and microscale combustion calorimetry (MCC) test. The results of MCC showed that the peak of heat release rate and total heat release of PLA/starch biocomposites decreased dramatically compared with those of pure PLA. The thermal degradation and gas products of PLA/starch/MCAPP systems were monitored by thermogravimetric analysis and thermogravimetric analysis−infrared spectrometry. Scanning electron microscopy and X-ray photoelectron spectroscopy were utilized to explore the surface morphology and chemical components of the char residues.

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Metadata

Authors
Wang, X., Hu, Y., Song, L., Xuan, S., Xing, W., Bai, Z., & Lu, H.
Venue
Industrial & Engineering Chemistry Research
Published
2011-01-19
Volume
50
Issue
2
Pages
713-720
ISSN
  • 0888-5885 (ISSN-L)
  • 1520-5045
OpenAlex
W2312829695
Cited by
194
References
0
FWCI
6.02
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Flame Retardancy and Thermal Degradation of Intumescent Flame Retardant Poly(lactic acid)/Starch Biocomposites. https://app.cochat.ai/papers/10.1021/ie1017157
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Wang, X., Hu, Y., Song, L., Xuan, S., Xing, W., Bai, Z., & Lu, H. (2011). Flame Retardancy and Thermal Degradation of Intumescent Flame Retardant Poly(lactic acid)/Starch Biocomposites. Industrial & Engineering Chemistry Research. https://doi.org/10.1021/ie1017157

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