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Comprehensive Investigation on the Thermal Stability of 66 Ionic Liquids by Thermogravimetric Analysis

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Cao, Yuanyuan, Mu, Tiancheng·2014·Industrial & Engineering Chemistry Research

Abstract

The thermal stabilities of 66 ionic liquids (ILs) were investigated using the thermogravimetric analysis (TGA) method. Isothermal TGA studies on the ILs showed that ILs exhibit decomposition at temperatures lower than the onset decomposition temperature ( T onset ), which is determined from ramped temperature TGA experiments. Thermal decomposition kinetics of ILs was analyzed using pseudo-zero-order rate expression and their activation energy was obtained. Parameter T 0.01/10h, the temperature at which 1% mass loss occurs in 10 h, was used to evaluate the long-term thermal stability of ILs. The thermal stability of the ILs was classified to five levels according to T onset . The ILs thermal stability is dependent on the structure of ILs, i.e., cation modification, cation and anion type. The correlations between the stability and the hydrophilicity of ILs were discussed. Finally, the thermal stabilities of acetate-based ILs, amino acid ILs, and dicyanamide ILs were analyzed.

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Metadata

Authors
Cao, Y., & Mu, T.
Venue
Industrial & Engineering Chemistry Research
Published
2014-05-12
Volume
53
Issue
20
Pages
8651-8664
ISSN
  • 0888-5885 (ISSN-L)
  • 1520-5045
OpenAlex
W2327269997
Cited by
851
References
64
FWCI
11.99
Type
journal article
Language
en
Open access
hybrid

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Cao, Y., & Mu, T. (2014). Comprehensive Investigation on the Thermal Stability of 66 Ionic Liquids by Thermogravimetric Analysis. Industrial & Engineering Chemistry Research. https://doi.org/10.1021/ie5009597

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