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Algebraic Representation of Thermodynamic Properties and the Classification of Solutions
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ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTAlgebraic Representation of Thermodynamic Properties and the Classification of SolutionsOtto Redlich and A. T. KisterCite this: Ind. Eng. Chem. 1948, 40, 2, 345–348Publication Date (Print):February 1, 1948Publication History Published online1 May 2002Published inissue 1 February 1948https://pubs.acs.org/doi/10.1021/ie50458a036https://doi.org/10.1021/ie50458a036research-articleACS PublicationsRequest reuse permissionsArticle Views5957Altmetric-Citations5126LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access options Get e-Alerts
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“The solid activity coefficients of CaCO3 () and MnCO3 () in terms of solid components (1−x, x) can be estimated by the Redlich and Kister equations [50, 54, 60], which are expressed as:1617 where 1−x and x are the molar ratios ( and ) of CaCO3 and MnCO3 in the (Ca1-xMnx)CO3 solid solutions, respectively.”
From Dissolution and solubility of calcite-rhodochrosite solid solutions [(Ca1-xMnx)CO3] at 25 °C (2021) · cites this paper as [60]
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“To accomplish this dependence, Redlich and Kister (1948) and McGlashan (1963) used a power series expansion in xorg of the following form: GE/RT = xorg ( 1− xorg )[ c′1+ c ′ 2 ( 1− 2xorg ) + . . . + c′n ( 1− 2xorg )n−1] .”
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“…case of (Mn,Ca)CO3 solid solution, the activity of the solid components (gCa, gMn) can be derived by the following Redlich and Kister expressions (Redlich and Kister, 1948; Plummer and Busenberg, 1982): ln gCa ¼ ðGE XMn dGE dXMn Þ=RT ð7Þ ln gMn ¼ ðGE þ XCa dGE dXMn Þ=RT ð8Þ where R is the gas…”
Metadata
- Authors
- Redlich, O., & Kister, A. T.
- Venue
- Industrial & Engineering Chemistry
- Publisher
- American Chemical Society (ACS)
- Published
- 1948-02
- Volume
- 40
- Issue
- 2
- Pages
- 345-348
- ISSN
- 0019-7866 (ISSN-L)
- 1541-5724
- OpenAlex
- W1991410388
- Cited by
- 5,879
- References
- 0
- Citations by year
- 2026: 192 · 2025: 262 · 2024: 270 · 2023: 215 · 2022: 219 · 2021: 241 · 2020: 254 · 2019: 240 · 2018: 230 · 2017: 243 · 2016: 226 · 2015: 219 · 2014: 251 · 2013: 254 · 2012: 220
- FWCI
- 1.41
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Industrial & Engineering Chemistry (publishedVersion)
- Topics
- Physical Sciences › Chemistry › Physical and Theoretical Chemistry › Phase Equilibria and Thermodynamics
- Physical Sciences › Chemical Engineering › Fluid Flow and Transfer Processes › Thermodynamic properties of mixtures
- Physical Sciences › Chemistry › Organic Chemistry › Chemical Thermodynamics and Molecular Structure
- Keywords
- thermodynamic properties, algebraic representation, classification of solutions, thermodynamic equations of state
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