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NEW METHOD FOR PREDICTION OF BINARY GAS-PHASE DIFFUSION COEFFICIENTS
Abstract
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTNEW METHOD FOR PREDICTION OF BINARY GAS-PHASE DIFFUSION COEFFICIENTSEdward N. Fuller, Paul D. Schettler, and J. Calvin. GiddingsCite this: Ind. Eng. Chem. 1966, 58, 5, 18–27Publication Date (Print):May 1, 1966Publication History Published online1 May 2002Published inissue 1 May 1966https://pubs.acs.org/doi/10.1021/ie50677a007https://doi.org/10.1021/ie50677a007research-articleACS PublicationsRequest reuse permissionsArticle Views12407Altmetric-Citations1654LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access options Get e-Alerts
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“The maximum operating temperature of the membrane, is typically 90 °C and should not be exceeded so as to avoid reduced proton mobility through the membrane, [154] as well as flooding due to increased water crossover from the anode.[145,250]”
From Electrochemical CO 2 Reduction into Chemical Feedstocks: From Mechanistic Electrocatalysis Models to System Design (2019) · cites this paper as [250]
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“The effective diffusion coefficient for oxygen given by Millington (1959) was modified through including the temperature correction by Fuller, Schettler, and Giddings (1966).”
BackgroundMethodInfluentialEffective Diffusivity Measurements on Porous Catalyst Pellets at Elevated Temperature and Pressure
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“diesel (n-C12H26) Tbn NIST LTbn NIST ρl NIST cp,l NIST μl NIST σ Brock [46] cp,v NIST μv Lucas [47] kv Modified Eucken method [48] Dv,a Fuller [49,50] pv NIST”
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“Binary diffusion coefficient is evaluated by Fuller’s model (Fuller et al. 1966) with Takahashi’s correction (Takahashi 1975).”
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“…for water vapor in free air at the given soil temperatures is calculated using an empirical fit to experimental measurements made at 1 atm pressure over a wide range of temperatures [Fuller et al., 1966]: Dv ¼ 1:176 10 9 Tav1:75 (3) where Tav is the average temperature for each soil layer.”
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“1 is the sum of atomic diffusion volume for molecule.(26) The average 20 distance for CH4 molecules to diffuse into the channel is about a = 3 cm, therefore 21 Page 10 of 27 Nanoscale”
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“…of the three noble gases used, its diffusion coefficient in air is closest to that of CH4 (Ar = 1.81 10 5, CH4 = 2.05 10 5 m2 s 1 at 20 C, from Fuller et al. (1966) and Ar was previous shown in abiotic studies to be the most similar tracer to CH4 during GPPTs (Gonzalez-Gil et al., 2007; Gomez…”
BackgroundInfluentialZhong, G., Xie, Z., Möller, A., et al. (2012) · Environmental Chemistry · doi:10.1071/en12065 · Cited by 19
“Dair was calculated using the method described by Fuller et al.([15]) and Sc for the pesticides was calculated using the method described by Hayduk and Laudi.”
MethodAnalysis of Leakages in a Solid Oxide Fuel Cell Stack in a System Environment
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“Using correlations with molecular weight (Fuller et al., 1966), we estimated Da,ethanol=1.1 m 2/day, Da,MTBE=0.7 m 2/day, and Da,ethylbenz=0.7 m 2/day.”
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Transport and fate of volatile organic chemicals in unsaturated, nonisothermal, salty porous media:
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“(6), the method of Fuller et al. (1966) is used to calculate the gas-phase diffusivities.”
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“The mass diffusion coefficient was determined using the following formula [23]:”
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“…speed (Mackay and Yeun 1983; Swarzenbach et al. 2003), ka ~ (0:3 z 0:2u10) DatmDMS DatmO2 " #0:67 ð6Þ The diffusivity of DMS in the atmosphere was determined using the relationship of Fuller et al. (1966) and is corrected for air temperature (Kelvin), atmospheric pressure (atm), and molar volume.”
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“In [15, 16], Fuller and co authors defined specific values of diffusion volumes for some molecules, which do not always coincide with the corresponding summation procedure of atomic diffusion volumes.”
BackgroundMethodInfluentialLiu, S., Xu, F., Lu, B., et al. (2023) · Powder Technology · doi:10.1016/j.powtec.2023.119099 · Cited by 17
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Metadata
- Authors
- Fuller, E. N., Schettler, P. D., & Giddings, J. C.
- Venue
- Industrial & Engineering Chemistry
- Publisher
- American Chemical Society (ACS)
- Published
- 1966-05-01
- Volume
- 58
- Issue
- 5
- Pages
- 18-27
- ISSN
- 0019-7866 (ISSN-L)
- 1541-5724
- OpenAlex
- W2075886908
- Cited by
- 2,515
- References
- 0
- Citations by year
- 2026: 141 · 2025: 141 · 2024: 160 · 2023: 130 · 2022: 148 · 2021: 136 · 2020: 134 · 2019: 124 · 2018: 113 · 2017: 108 · 2016: 101 · 2015: 81 · 2014: 99 · 2013: 71 · 2012: 99
- FWCI
- 2.12
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Industrial & Engineering Chemistry (publishedVersion)
- Topics
- Physical Sciences › Chemistry › Physical and Theoretical Chemistry › Diffusion Coefficients in Liquids
- Physical Sciences › Chemistry › Physical and Theoretical Chemistry › Adsorption, diffusion, and thermodynamic properties of materials
- Physical Sciences › Mathematics › Applied Mathematics › Gas Dynamics and Kinetic Theory
- Keywords
- diffusion coefficient, forecasting methods, gas mixtures, transport properties
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
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