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Olefin/Paraffin Separations by Reactive Absorption: A Review
Abstract
Light olefins and paraffins are commonly separated by cryogenic distillation. A process based upon reversible chemical complexation, which employs a mass-separating agent rather than an energy-separating agent, presents an attractive alternative to distillation. Use of such a facilitated-transport-assisted process could substantially reduce the capital costs and energy requirements of olefin/paraffin separations. Copper(I) and silver(I) have long been known to form electron donor/acceptor complexes with olefins. Several chemical systems using these transition metals as the selective separating agent have been studied. A review of copper- and silver-based complexing solutions for olefin/paraffin separations via gas/liquid contacting is presented.
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Citations
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Olefin/paraffin separation technology: a review
Eldridge, R. B. (1993) · Industrial & Engineering Chemistry Research · doi:10.1021/ie00022a002 · Cited by 746
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Cited by
Metal–Organic Frameworks for Separations
Li, J.-R., Sculley, J., & Zhou, H.-C. (2012) · Chemical Reviews · doi:10.1021/cr200190s · Cited by 6,323
Control of zeolite framework flexibility and pore topology for separation of ethane and ethylene
Bereciartua, P. J., Cantín, Á., Corma, A., Jordá, J. L., Palomino, M., Rey, F., Valencia, S., Corcoran, E. W., Kortunov, P., Ravikovitch, P. I., et al. (2017) · Science · doi:10.1126/science.aao0092 · Cited by 460
Wang, Y., Peh, S. B., & Zhao, D. (2019) · Small · doi:10.1002/smll.201900058 · Cited by 342
Nijem, N., Wu, H., Canepa, P., Marti, A., Balkus, K. J., Thonhauser, T., Li, J., & Chabal, Y. J. (2012) · Journal of the American Chemical Society · doi:10.1021/ja305754f · Cited by 308
Khan, N. A., & Jhung, S. H. (2017) · Journal of Hazardous Materials · doi:10.1016/j.jhazmat.2016.11.070 · Cited by 308
Metadata
- Authors
- Safarik, D. J., & Eldridge, R. B.
- Venue
- Industrial & Engineering Chemistry Research
- Publisher
- American Chemical Society (ACS)
- Published
- 1998-06-02
- Volume
- 37
- Issue
- 7
- Pages
- 2571-2581
- ISSN
- 0888-5885 (ISSN-L)
- 1520-5045
- OpenAlex
- W2080507319
- Cited by
- 352
- References
- 1
- FWCI
- 16.26
- Type
- journal article
- Language
- en
- Open access
- closed
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
