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ON THE THEORY OF OXIDATION—REDUCTION REACTIONS INVOLVING ELECTRON TRANSFER. V. COMPARISON AND PROPERTIES OF ELECTROCHEMICAL AND CHEMICAL RATE CONSTANTS1
Open accessAbstract
Using a theory of electron transfers which takes cognizance of reorganization of the medium outside the inner coordination shell and of changes of bond lengths inside it, relations between electrochemical and related chemical rate constants are deduced and compared with the experimental data. A correlation is found, without the use of arbitrary parameters. Effects of weak complexes with added electrolytes are included under specified conditions. The deductions offer a way of coordinating a variety of data in the two fields, internally as well as with each other, and a way of predicting results in one field from those in another. For example, the rate of oxidation or reduction of a series of related reactants by one reagent is correlated with that of another and with that of the corresponding electrochemical oxidation-reduction reaction, under certain specified conditions. These correlations may also provide a test for distinguishing an electron from an atom transfer mechanism.
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Citations
Cited by
Electron transfer reactions in chemistry. Theory and experiment
Marcus, R. A. (1993) · Reviews of Modern Physics · doi:10.1103/revmodphys.65.599 · Cited by 3,667
Self-citationThe biochemistry and medical significance of the flavonoids
Havsteen, B. H. (2002) · Pharmacology & Therapeutics · doi:10.1016/s0163-7258(02)00298-x · Cited by 2,672
Implicit Solvation Models: Equilibria, Structure, Spectra, and Dynamics
Cramer, C. J., & Truhlar, D. G. (1999) · Chemical Reviews · doi:10.1021/cr960149m · Cited by 2,308
Electron Transfer Reactions in Chemistry: Theory and Experiment (Nobel Lecture)
Marcus, R. A. (1993) · Angewandte Chemie International Edition in English · doi:10.1002/anie.199311113 · Cited by 1,915
Self-citationComputational electrochemistry: prediction of liquid-phase reduction potentials
Marenich, A. V., Ho, J., Coote, M. L., Cramer, C. J., & Truhlar, D. G. (2014) · Phys. Chem. Chem. Phys. · doi:10.1039/c4cp01572j · Cited by 508
Fabrication and Use of Nanometer-Sized Electrodes in Electrochemistry
Penner, R. M., Heben, M. J., Longin, T. L., & Lewis, N. S. (1990) · Science · doi:10.1126/science.250.4984.1118 · Cited by 356
Theoretical Modeling of Electrochemical Proton-Coupled Electron Transfer
Warburton, R. E., Soudackov, A. V., & Hammes-Schiffer, S. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.1c00929 · Cited by 322
On the Theory of Chemiluminescent Electron-Transfer Reactions
Marcus, R. A. (1965) · The Journal of Chemical Physics · doi:10.1063/1.1697190 · Cited by 260
Self-citation(2016) · Advances in Botanical Research · doi:10.1016/bs.abr.2016.04.001 · Cited by 3
Metadata
- Authors
- Marcus, R. A.
- Venue
- The Journal of Physical Chemistry
- Publisher
- American Chemical Society (ACS)
- Published
- 1963-04
- Volume
- 67
- Issue
- 4
- Pages
- 853-857
- ISSN
- 0022-3654 (ISSN-L)
- 1541-5740
- OpenAlex
- W2018201939
- Cited by
- 691
- References
- 0
- FWCI
- 2.58
- Type
- journal article
- Language
- en
- Open access
- green
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