The DOI matches its Crossref record.
Measurement of the Hydride Donor Abilities of [HM(diphosphine)2]+ Complexes (M = Ni, Pt) by Heterolytic Activation of Hydrogen
Abstract
[M(diphosphine)2]2+ complexes (where M = Ni and Pt) react with hydrogen in the presence of bases to form the corresponding hydrides, [HM(diphosphine)2]+. In seven cases, equilibria have been observed from which the hydride donor ability (DeltaGdegrees(H-)) of the hydrides can be calculated. For six of these complexes, the DeltaGdegrees(H-) values calculated using heterolytic activation of hydrogen are compared with those based on thermodynamic cycles using pK(a) measurements and electrochemical half-wave potentials. The agreement between these two methods is good (within 1 kcal/mol). The reactivity of the various [M(diphosphine)2]2+ complexes toward hydrogen parallels their measured hydride acceptor abilities.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cited by
Clapham, S. E., Hadzovic, A., & Morris, R. H. (2004) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2004.04.007 · Cited by 1,316
Liu, P., & Rodriguez, J. A. (2005) · Journal of the American Chemical Society · doi:10.1021/ja0540019 · Cited by 1,240
Artificial photosynthesis: opportunities and challenges of molecular catalysts
Zhang, B., & Sun, L. (2019) · Chemical Society Reviews · doi:10.1039/c8cs00897c · Cited by 954
A Cobalt-Based Catalyst for the Hydrogenation of CO2 under Ambient Conditions
Jeletic, M. S., Mock, M. T., Appel, A. M., & Linehan, J. C. (2013) · Journal of the American Chemical Society · doi:10.1021/ja406601v · Cited by 391
Production of hydrogen by electrocatalysis: making the H–H bond by combining protons and hydrides
Bullock, R. M., Appel, A. M., & Helm, M. L. (2014) · Chem. Commun. · doi:10.1039/c3cc46135a · Cited by 281
Metadata
- Authors
- Curtis, C. J., Miedaner, A., Ellis, W. W., & DuBois, D. L.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2002-02-08
- Volume
- 124
- Issue
- 9
- Pages
- 1918-1925
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2015927108
- Cited by
- 240
- References
- 0
- FWCI
- 7.33
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Measurement of the Hydride Donor Abilities of [HM(diphosphine)2]+ Complexes (M = Ni, Pt) by Heterolytic Activation of Hydrogen. https://app.cochat.ai/papers/10.1021/ja0116829
- The paper
- Curtis, C. J., Miedaner, A., Ellis, W. W., & DuBois, D. L. (2002). Measurement of the Hydride Donor Abilities of [HM(diphosphine)2]+ Complexes (M = Ni, Pt) by Heterolytic Activation of Hydrogen. Journal of the American Chemical Society. https://doi.org/10.1021/ja0116829
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
