The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Arresting Butterfly-Like Intermediate Nanocrystals of β-Co(OH)2 via Ethylenediamine-Mediated Synthesis
Abstract
A synthesis of beta-Co(OH)2 nanocrystalline materials has been investigated with the assistance of chelating agent ethylenediamine. By controlling precipitation processes, various forms of beta-Co(OH)2 crystallites can be prepared at different stages. The crystallite morphologies include two-dimensional hexagonal sheet platelets, one-dimensional nanorods, and butterfly-like nanocrystallite intermediates. In particular, a triangular construction unit for beta-Co(OH)2 crystallites has been revealed with the ethylenediamine mediation in the synthesis. With the successful arrest of these butterfly-like intermediate crystallites, especially of linearly aligned "butterflies", the formation mechanism of one-dimensional nanorods or nanoribbons has been experimentally explained. The chemical composition of solution precursors and resultant beta-Co(OH)2 crystallites has been analyzed with UV-vis/FTIR/CHN /XRD/TGA/TEM/SAED methods. The relationships among various observed crystallite morphologies have also been discussed on the basis of the experimental findings.
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Citations
Cites
Shape control of CdSe nanocrystals
Peng, X., Manna, L., Yang, W., Wickham, J., Scher, E., Kadavanich, A., & Alivisatos, A. P. (2000) · Nature · doi:10.1038/35003535 · Cited by 4,487
Cited by
Synthetic architecture of interior space for inorganic nanostructures
Zeng, H. C. (2006) · J. Mater. Chem. · doi:10.1039/b511296f · Cited by 462
Self-citationHydrothermal Synthesis of α-MoO3Nanorods via Acidification of Ammonium Heptamolybdate Tetrahydrate
Lou, X. W., & Zeng, H. C. (2002) · Chemistry of Materials · doi:10.1021/cm0206237 · Cited by 377
Self-citationYun, X., Lu, T., Zhou, R., Lu, Z., Li, J., & Zhu, Y. (2021) · Chemical Engineering Journal · doi:10.1016/j.cej.2021.131328 · Cited by 228
Metadata
- Authors
- Sampanthar, J. T., & Zeng, H. C.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2002-05-17
- Volume
- 124
- Issue
- 23
- Pages
- 6668-6675
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2021531082
- Cited by
- 199
- References
- 1
- FWCI
- 7.95
- Type
- journal article
- Language
- en
- Open access
- closed
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