The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Stereoselective Ring-Opening Polymerization of Racemic Lactide Using Aluminum-Achiral Ligand Complexes: Exploration of a Chain-End Control Mechanism
Abstract
Stereoselective polymerization of racemic lactide (rac-LA) was examined using Al-achiral ligand complexes. By introduction of substituents in aromatic rings of Schiff base ligands, a higher selectivity was obtained without any chiral auxiliaries in the catalyst via a chain-end control mechanism. The T(m) values (T(m) 170-192 degrees C) were comparable to or higher than that of homochiral polymer, poly(L-LA) (T(m) 162 degrees C), and a thermally more stable polylactide than poly(L-LA) was prepared from rac-LA.
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Citations
Cites
Stereocomplex formation between enantiomeric poly(lactides)
Ikada, Y., Jamshidi, K., Tsuji, H., & Hyon, S. H. (1987) · Macromolecules · doi:10.1021/ma00170a034 · Cited by 1,409
Ovitt, T. M., & Coates, G. W. (1999) · Journal of the American Chemical Society · doi:10.1021/ja990088k · Cited by 502
Radano, C. P., Baker, G. L., & Smith, M. R. (2000) · Journal of the American Chemical Society · doi:10.1021/ja9930519 · Cited by 403
Cited by
Controlled Ring-Opening Polymerization of Lactide and Glycolide
Dechy-Cabaret, O., Martin-Vaca, B., & Bourissou, D. (2004) · Chemical Reviews · doi:10.1021/cr040002s · Cited by 2,257
Catalysis as an Enabling Science for Sustainable Polymers
Zhang, X., Fevre, M., Jones, G. O., & Waymouth, R. M. (2018) · Chemical Reviews · doi:10.1021/acs.chemrev.7b00329 · Cited by 936
Thomas, C. M. (2010) · Chem. Soc. Rev. · doi:10.1039/b810065a · Cited by 853
WU, J., YU, T., CHEN, C., & LIN, C. (2006) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2005.07.010 · Cited by 779
Biocompatible Initiators for Lactide Polymerization
Platel, R., Hodgson, L., & Williams, C. (2008) · Polymer Reviews · doi:10.1080/15583720701834166 · Cited by 706
Metadata
- Authors
- Nomura, N., Ishii, R., Akakura, M., & Aoi, K.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2002-05-01
- Volume
- 124
- Issue
- 21
- Pages
- 5938-5939
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2047814327
- Cited by
- 478
- References
- 3
- FWCI
- 8.72
- Type
- journal article
- Language
- en
- Open access
- closed
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- Nomura, N., Ishii, R., Akakura, M., & Aoi, K. (2002). Stereoselective Ring-Opening Polymerization of Racemic Lactide Using Aluminum-Achiral Ligand Complexes: Exploration of a Chain-End Control Mechanism. Journal of the American Chemical Society. https://doi.org/10.1021/ja0175789
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