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Aqueous Room Temperature Metal-Catalyzed Living Radical Polymerization of Vinyl Chloride
Abstract
This paper describes the room-temperature living radical polymerization (LRP) of vinyl chloride in H2O/THF in the presence of Cu0 or CuI salts as catalysts, tren or PEI as ligands, and iodoform as initiator. The disproportionation reaction 2CuI + L --> Cu0 + CuII(L) is the crucial step, as it continuously provides the active species for both the initiation (Cu0) and the reversible termination step (CuII). Mn was found to increase linearly with conversion and is in good agreement with Mth, with the Mw/Mn being approximately 1.5.
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Citations
Cites
Kato, M., Kamigaito, M., Sawamoto, M., & Higashimura, T. (1995) · Macromolecules · doi:10.1021/ma00109a056 · Cited by 3,046
Cited by
Controlled/living radical polymerization: Features, developments, and perspectives
Braunecker, W. A., & Matyjaszewski, K. (2007) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2006.11.002 · Cited by 3,202
Nanostructured functional materials prepared by atom transfer radical polymerization
Matyjaszewski, K., & Tsarevsky, N. V. (2009) · Nature Chemistry · doi:10.1038/nchem.257 · Cited by 1,258
Ouchi, M., Terashima, T., & Sawamoto, M. (2009) · Chemical Reviews · doi:10.1021/cr900234b · Cited by 1,257
Satoh, K., & Kamigaito, M. (2009) · Chemical Reviews · doi:10.1021/cr900115u · Cited by 302
Zoppe, J. O., Habibi, Y., Rojas, O. J., Venditti, R. A., Johansson, L.-S., Efimenko, K., Österberg, M., & Laine, J. (2010) · Biomacromolecules · doi:10.1021/bm100719d · Cited by 283
Metadata
- Authors
- Percec, V., Popov, A. V., Ramirez-Castillo, E., Monteiro, M., Barboiu, B., Weichold, O., Asandei, A. D., & Mitchell, C. M.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2002-04-12
- Volume
- 124
- Issue
- 18
- Pages
- 4940-4941
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W1977308241
- Cited by
- 421
- References
- 1
- FWCI
- 10.02
- Type
- journal article
- Language
- en
- Open access
- closed
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- The paper
- Percec, V., Popov, A. V., Ramirez-Castillo, E., Monteiro, M., Barboiu, B., Weichold, O., Asandei, A. D., & Mitchell, C. M. (2002). Aqueous Room Temperature Metal-Catalyzed Living Radical Polymerization of Vinyl Chloride. Journal of the American Chemical Society. https://doi.org/10.1021/ja0256055
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
