The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
EXAFS Investigations of the Mechanism of Facilitated Ion Transfer into a Room-Temperature Ionic Liquid
Abstract
The Sr(II)-crown ether complexes formed in a room-temperature ionic liquid (RTIL), 1-methyl-3-pentylimidazolium bis[(trifluoromethyl)sulfonyl]amide, have been studied by X-ray absorption fine structure measurements at the Sr K-edge. When a Sr(NO(3))(2)-crown ether complex is directly dissolved in a water-saturated RTIL, both nitrate ligands and the crown ether coordinate the Sr, as observed in a conventional two-phase water-octanol system. When the cationic Sr-crown ether complex is created in a two-phase water-RTIL system, however, only cationic Sr-crown ether complexes are observed in the RTIL phase. This difference in the coordination complexes arises from differences in the mechanism of cation extraction between the RTIL and conventional molecular organic solvents, a finding with important implications for synthesis, catalysis, and ion separations using two-phase water-RTIL systems.
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Citations
Cites
pH-Dependent partitioning in room temperature ionic liquids
Visser, A. E., Swatloski, R. P., & Rogers, R. D. (2000) · Green Chemistry · doi:10.1039/a908888a · Cited by 281
Cited by
Ionic Liquids-Based Extraction: A Promising Strategy for the Advanced Nuclear Fuel Cycle
Sun, X., Luo, H., & Dai, S. (2012) · Chemical Reviews · doi:10.1021/cr200193x · Cited by 852
Dietz, M. L., Dzielawa, J. A., Laszak, I., Young, B. A., & Jensen, M. P. (2003) · Green Chem. · doi:10.1039/b310507p · Cited by 276
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Metadata
- Authors
- Jensen, M. P., Dzielawa, J. A., Rickert, P., & Dietz, M. L.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2002-08-16
- Volume
- 124
- Issue
- 36
- Pages
- 10664-10665
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2006302195
- Cited by
- 219
- References
- 1
- FWCI
- 4.56
- Type
- journal article
- Language
- en
- Open access
- closed
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