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Biomimetic Arrays of Oriented Helical ZnO Nanorods and Columns
Abstract
Extended helical or chiral nanostructures are usually associated with biomolecules but are mostly absent in synthetic materials. Here we report the first synthesis of unusual oriented and extended helical nanostructures in synthetic ceramics. Large arrays of oriented helical ZnO nanorods and columns are formed using simple citrate ions to control the growth habits of the ZnO crystal. This novel mechanism could lead to new approaches to control the orientation, the surface area, and the defect structure of synthetic materials that are critical for practical applications. The morphology generated in the helical ZnO nanostructure shows remarkable resemblance to the growth morphology of nacreous calcium carbonate and thus may shed new light on morphology and orientation control of biominerals.
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Citations
Cited by
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Tian, Z. R., Voigt, J. A., Liu, J., Mckenzie, B., Mcdermott, M. J., Rodriguez, M. A., Konishi, H., & Xu, H. (2003) · Nature Materials · doi:10.1038/nmat1014 · Cited by 1,454
Self-citationControlling Mineral Morphologies and Structures in Biological and Synthetic Systems
Meldrum, F. C., & Cölfen, H. (2008) · Chemical Reviews · doi:10.1021/cr8002856 · Cited by 1,397
One-dimensional ZnO nanostructures: Solution growth and functional properties
Xu, S., & Wang, Z. L. (2011) · Nano Research · doi:10.1007/s12274-011-0160-7 · Cited by 1,361
A Comprehensive Review of Glucose Biosensors Based on Nanostructured Metal-Oxides
Rahman, M. M., Ahammad, A. J. S., Jin, J.-H., Ahn, S. J., & Lee, J.-J. (2010) · Sensors · doi:10.3390/s100504855 · Cited by 762
Reduced Graphene Oxide Conjugated Cu2O Nanowire Mesocrystals for High-Performance NO2 Gas Sensor
Deng, S., Tjoa, V., Fan, H. M., Tan, H. R., Sayle, D. C., Olivo, M., Mhaisalkar, S., Wei, J., & Sow, C. H. (2012) · Journal of the American Chemical Society · doi:10.1021/ja211683m · Cited by 757
Metadata
- Authors
- Tian, Z. R., Voigt, J. A., Liu, J., Mckenzie, B., & Mcdermott, M. J.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2002-10-09
- Volume
- 124
- Issue
- 44
- Pages
- 12954-12955
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2064301426
- Cited by
- 492
- References
- 0
- FWCI
- 20.35
- Type
- journal article
- Language
- en
- Open access
- closed
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- Tian, Z. R., Voigt, J. A., Liu, J., Mckenzie, B., & Mcdermott, M. J. (2002). Biomimetic Arrays of Oriented Helical ZnO Nanorods and Columns. Journal of the American Chemical Society. https://doi.org/10.1021/ja0279545
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