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A Direct Catalytic Asymmetric Mannich-type Reaction to syn-Amino Alcohols
Abstract
The Mannich reaction is one of the most widely utilized chemical transformations for the construction of nitrogen-containing compounds. With the increasing occurrence of nitrogen in drugs and natural products, highly asymmetric variants of the Mannich reaction are desirable. In this communication, we report the application of our dinuclear zinc catalyst to a highly asymmetric Mannich-type reaction to generate syn 1,2-amino alcohols.
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Cited by
“Designer Acids”: Combined Acid Catalysis for Asymmetric Synthesis
Yamamoto, H., & Futatsugi, K. (2005) · Angewandte Chemie International Edition · doi:10.1002/anie.200460394 · Cited by 688
Direct Asymmetric anti-Mannich-Type Reactions Catalyzed by a Designed Amino Acid
Mitsumori, S., Zhang, H., Ha-Yeon Cheong, P., Houk, K. N., Tanaka, F., & Barbas, C. F. (2006) · Journal of the American Chemical Society · doi:10.1021/ja056984f · Cited by 305
In Situ Versus Isolated Zinc Catalysts in the Selective Synthesis of Homo and Multi-block Polyesters
Gruszka, W., Walker, L. C., Shaver, M. P., & Garden, J. A. (2020) · Macromolecules · doi:10.1021/acs.macromol.0c00277 · Cited by 49
Metadata
- Authors
- Trost, B. M., & Terrell, L. R.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2002-12-13
- Volume
- 125
- Issue
- 2
- Pages
- 338-339
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2029694100
- Cited by
- 339
- References
- 0
- FWCI
- 17.84
- Type
- journal article
- Language
- en
- Open access
- closed
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Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
