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Synthesis of Polyaniline Nanofibers by “Nanofiber Seeding”
Abstract
Seeding a conventional chemical oxidative polymerization of aniline with even very small amounts of biological, inorganic, or organic nanofibers (usually <1%) dramatically changes the morphology of the resulting doped electronic polymer polyaniline from nonfibrillar (particulate) to almost exclusively nanofibers. The nanoscale morphology of the original seed template is transcribed almost quantitatively to the bulk precipitate. These findings could have immediate impact in the design and development of high-surface area electronic materials.
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Cited by
Polyaniline nanostructures and the role of aniline oligomers in their formation
Stejskal, J., Sapurina, I., & Trchová, M. (2010) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2010.07.006 · Cited by 799
Nanofiber Formation in the Chemical Polymerization of Aniline: A Mechanistic Study
Huang, J., & Kaner, R. B. (2004) · Angewandte Chemie International Edition · doi:10.1002/anie.200460616 · Cited by 756
Polyaniline Nanofibers Prepared by Dilute Polymerization
Chiou, N. ‐., & Epstein, A. J. (2005) · Advanced Materials · doi:10.1002/adma.200401000 · Cited by 562
Shape and Aggregation Control of Nanoparticles: Not Shaken, Not Stirred
Li, D., & Kaner, R. B. (2006) · Journal of the American Chemical Society · doi:10.1021/ja056609n · Cited by 548
Conducting Polyaniline Nanowire and Its Applications in Chemiresistive Sensing
Song, E., & Choi, J.-W. (2013) · Nanomaterials · doi:10.3390/nano3030498 · Cited by 462
Wang, X.-X., Yu, G.-F., Zhang, J., Yu, M., Ramakrishna, S., & Long, Y.-Z. (2021) · Progress in Materials Science · doi:10.1016/j.pmatsci.2020.100704 · Cited by 447
Conducting Polymer Nanomaterials and Their Applications
Jang, J. (2006) · Advances in Polymer Science · doi:10.1007/12_075 · Cited by 425
The intrinsic nanofibrillar morphology of polyaniline
Huang, J., & Kaner, R. B. (2006) · Chem. Commun. · doi:10.1039/b510956f · Cited by 419
A review on advances in application of polyaniline for ammonia detection
Tanguy, N. R., Thompson, M., & Yan, N. (2018) · Sensors and Actuators B: Chemical · doi:10.1016/j.snb.2017.11.008 · Cited by 284
Carboxyl-functionalized graphene oxide–polyaniline composite as a promising supercapacitor material
Liu, Y., Deng, R., Wang, Z., & Liu, H. (2012) · Journal of Materials Chemistry · doi:10.1039/c2jm32479b · Cited by 267
Metadata
- Authors
- Zhang, X., Goux, W. J., & Manohar, S. K.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2004-03-23
- Volume
- 126
- Issue
- 14
- Pages
- 4502-4503
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2021838640
- Cited by
- 691
- References
- 0
- FWCI
- 49.50
- Type
- journal article
- Language
- en
- Open access
- closed
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