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Cited by 599

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Standing Wave Enhancement of Red Absorbance and Photocurrent in Dye-Sensitized Titanium Dioxide Photoelectrodes Coupled to Photonic Crystals

Nishimura, Suzushi, Abrams, Neal, Lewis, Bradley A., Halaoui, Lara I., Mallouk, Thomas E., Benkstein, Kurt D., van de Lagemaat, Jao, Frank, Arthur J.·2003·Journal of the American Chemical Society
DOI 10.1021/ja034650p
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Abstract

The light harvesting efficiency of dye-sensitized photoelectrodes was enhanced by coupling a TiO(2) photonic crystal layer to a conventional film of TiO(2) nanoparticles. In addition to acting as a dielectric mirror, the inverse opal photonic crystal caused a significant change in dye absorbance which depended on the position of the stop band. Absorbance was suppressed at wavelengths shorter than the stop band maximum and was enhanced at longer wavelengths. This effect arises from the slow group velocity of light in the vicinity of the stop band, and the consequent localization of light intensity in the voids (to the blue) or in the dye-sensitized TiO(2) (to the red) portions of the photonic crystal. By coupling a photonic crystal to a film of TiO(2) nanoparticles, the short circuit photocurrent efficiency across the visible spectrum (400-750 nm) could be increased by about 26%, relative to an ordinary dye-sensitized nanocrystalline TiO(2) photoelectrode.

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Metadata

Authors
Nishimura, S., Abrams, N., Lewis, B. A., Halaoui, L. I., Mallouk, T. E., Benkstein, K. D., van de Lagemaat, J., & Frank, A. J.
Venue
Journal of the American Chemical Society
Publisher
American Chemical Society (ACS)
Published
2003-04-19
Volume
125
Issue
20
Pages
6306-6310
ISSN
  • 0002-7863 (ISSN-L)
  • 1520-5126
DOI
10.1021/ja034650p
OpenAlex
W2082864928
Cited by
599
References
1
FWCI
11.25
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Standing Wave Enhancement of Red Absorbance and Photocurrent in Dye-Sensitized Titanium Dioxide Photoelectrodes Coupled to Photonic Crystals. https://app.cochat.ai/papers/10.1021/ja034650p
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Nishimura, S., Abrams, N., Lewis, B. A., Halaoui, L. I., Mallouk, T. E., Benkstein, K. D., van de Lagemaat, J., & Frank, A. J. (2003). Standing Wave Enhancement of Red Absorbance and Photocurrent in Dye-Sensitized Titanium Dioxide Photoelectrodes Coupled to Photonic Crystals. Journal of the American Chemical Society. https://doi.org/10.1021/ja034650p

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