The DOI matches its Crossref record; 6 of the 6 references it cites were found in a registry or an index.
Bonding Self-Assembled, Compact Organophosphonate Monolayers to the Native Oxide Surface of Silicon
Open accessAbstract
A new method is described to prepare strongly bonded, compact monolayer films of alkyl- or arylphosphonates on the native oxide surface of Si (SiO(2)/Si). This method is illustrated for octadecyl- and alpha-quarterthiophene-2-phosphonates. For both cases, AFM shows comprehensive coverage of the SiO(2)/Si surface. The thickness of the continuous film of 4TP/SiO(2)/Si was measured both by AFM and by X-ray reflectivity to be ca. 18 A. Direct gravimetric analysis shows surface coverage by alpha-quarterthiophene-2-phosphonate to be about 0.66 nmol/cm(2), which corresponds to molecular packing in the film close to that of crystalline alpha-quarterthiophene. Coverage by octadecylphosphonate was ca. 0.90 nmol/cm(2), corresponding to a cross-sectional area of about 18.5 A(2)/molecule, consistent with close-packed alkyl chains.
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Cites
Organic Thin Film Transistors for Large Area Electronics
Dimitrakopoulos, C. D., & Malenfant, P. R. L. (2002) · Advanced Materials · doi:10.1002/1521-4095(20020116)14:2<99::aid-adma99>3.0.co;2-9 · Cited by 4,878
Insoluble monolayers at liquid-gas interfaces
Daen, J. (1966) · Journal of Colloid and Interface Science · doi:10.1016/0021-9797(66)90041-5 · Cited by 2,646
Organometallic Chemistry on Silicon and Germanium Surfaces
Buriak, J. M. (2002) · Chemical Reviews · doi:10.1021/cr000064s · Cited by 1,720
Rodahl, M., Höök, F., Krozer, A., Brzezinski, P., & Kasemo, B. (1995) · Review of Scientific Instruments · doi:10.1063/1.1145396 · Cited by 1,296
Organic chemical crystallography
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Alkyl Monolayers on Silicon Prepared from 1-Alkenes and Hydrogen-Terminated Silicon
Linford, M. R., Fenter, P., Eisenberger, P. M., & Chidsey, C. E. D. (1995) · Journal of the American Chemical Society · doi:10.1021/ja00116a019 · Cited by 1,104
Cited by
Covalent Surface Modification of Oxide Surfaces
Pujari, S. P., Scheres, L., Marcelis, A. T. M., & Zuilhof, H. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201306709 · Cited by 934
Surface Modification Using Phosphonic Acids and Esters
Queffélec, C., Petit, M., Janvier, P., Knight, D. A., & Bujoli, B. (2012) · Chemical Reviews · doi:10.1021/cr2004212 · Cited by 868
Self-assembled monolayers in organic electronics
Casalini, S., Bortolotti, C. A., Leonardi, F., & Biscarini, F. (2017) · Chemical Society Reviews · doi:10.1039/c6cs00509h · Cited by 608
Schmidt, H., Giustiniano, F., & Eda, G. (2015) · Chemical Society Reviews · doi:10.1039/c5cs00275c · Cited by 466
Hybrid materials from organophosphorus coupling molecules
Mutin, P. H., Guerrero, G., & Vioux, A. (2005) · Journal of Materials Chemistry · doi:10.1039/b505422b · Cited by 440
Metadata
- Authors
- Hanson, E. L., Schwartz, J., Nickel, B., Koch, N., & Danisman, M. F.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2003-11-25
- Volume
- 125
- Issue
- 51
- Pages
- 16074-16080
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2072463909
- Cited by
- 342
- References
- 6
- FWCI
- 8.04
- Type
- journal article
- Language
- en
- Open access
- green
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