The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Low-Temperature Synthesis of Soluble and Processable Organic-Capped Anatase TiO2 Nanorods
Abstract
We demonstrate the controlled growth of high aspect ratio anatase TiO2 nanorods by hydrolysis of titanium tetraisopropoxide (TTIP) in oleic acid (OLEA) as surfactant at a temperature as low as 80 degrees C. Chemical modification of TTIP by OLEA is proven to be a rational strategy to tune the reactivity of the precursor toward water. The most influential factors in shape control of the nanoparticles are investigated by simply manipulating their growth kinetics. The presence of tertiary amines or quaternary ammonium hydroxides as catalysts is essential to promote fast crystallization under mild conditions. The novelty of the present approach relies on the large-scale production of organic-capped TiO2 nanocrystals to which standard processing of colloidal nanocrystals, such as surface ligand exchange, can be applied for the first time. Concentrated colloidal titania dispersions can be prepared for a number of fundamental studies in homogeneous solutions and represent a new source of easily processable oxide material for many technological applications.
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Citations
Cites
A low-cost, high-efficiency solar cell based on dye-sensitized colloidal TiO2 films
O'Regan, B., & Grätzel, M. (1991) · Nature · doi:10.1038/353737a0 · Cited by 28,599
Shape control of CdSe nanocrystals
Peng, X., Manna, L., Yang, W., Wickham, J., Scher, E., Kadavanich, A., & Alivisatos, A. P. (2000) · Nature · doi:10.1038/35003535 · Cited by 4,487
Perspectives on the Physical Chemistry of Semiconductor Nanocrystals
Alivisatos, A. P. (1996) · The Journal of Physical Chemistry · doi:10.1021/jp9535506 · Cited by 3,595
Cited by
Chemistry and Properties of Nanocrystals of Different Shapes
Burda, C., Chen, X., Narayanan, R., & El-Sayed, M. A. (2005) · Chemical Reviews · doi:10.1021/cr030063a · Cited by 7,230
TiO2 photocatalysis: Design and applications
Nakata, K., & Fujishima, A. (2012) · Journal of Photochemistry and Photobiology C: Photochemistry Reviews · doi:10.1016/j.jphotochemrev.2012.06.001 · Cited by 3,651
Shape Control of Semiconductor and Metal Oxide Nanocrystals through Nonhydrolytic Colloidal Routes
Jun, Y., Choi, J., & Cheon, J. (2006) · Angewandte Chemie International Edition · doi:10.1002/anie.200503821 · Cited by 1,123
Liu, J., Bai, H., Wang, Y., Liu, Z., Zhang, X., & Sun, D. D. (2010) · Advanced Functional Materials · doi:10.1002/adfm.201001391 · Cited by 776
Tsai, C.-C., & Teng, H. (2006) · Chemistry of Materials · doi:10.1021/cm0518527 · Cited by 486
Metadata
- Authors
- Cozzoli, P. D., Kornowski, A., & Weller, H.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2003-10-31
- Volume
- 125
- Issue
- 47
- Pages
- 14539-14548
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2048003041
- Cited by
- 951
- References
- 3
- FWCI
- 26.99
- Type
- journal article
- Language
- en
- Open access
- closed
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- Cozzoli, P. D., Kornowski, A., & Weller, H. (2003). Low-Temperature Synthesis of Soluble and Processable Organic-Capped Anatase TiO2 Nanorods. Journal of the American Chemical Society. https://doi.org/10.1021/ja036505h
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