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Nanosized Molecular Propellers by Cyclodehydrogenation of Polyphenylene Dendrimers
Abstract
In a polymer analogous approach, large dendritic oligophenylenes containing benzene and tetraphenylmethane cores are transformed via oxidative cyclodehydrogenation to novel propeller-shaped molecules with large polycyclic aromatic hydrocarbon units as "blades". Structure analysis is performed by a combination of MALDI-TOF mass spectrometry, UV/vis, fluorescence, and Raman spectroscopy using solid-state sample preparation methods. These methods are also utilized to determine the degree of the cyclodehydrogenation reaction.
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Cited by
Graphenes as Potential Material for Electronics
Wu, J., Pisula, W., & Müllen, K. (2007) · Chemical Reviews · doi:10.1021/cr068010r · Cited by 2,723
Self-citationMa, J., Lin, T., Pan, X., & Wang, W. (2014) · Chemistry of Materials · doi:10.1021/cm501590w · Cited by 59
Metadata
- Authors
- Simpson, C. D., Mattersteig, G., Martin, K., Gherghel, L., Bauer, R. E., Räder, H. J., & Müllen, K.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2004-02-21
- Volume
- 126
- Issue
- 10
- Pages
- 3139-3147
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2010045253
- Cited by
- 169
- References
- 0
- FWCI
- 6.36
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Nanosized Molecular Propellers by Cyclodehydrogenation of Polyphenylene Dendrimers. https://app.cochat.ai/papers/10.1021/ja036732j
- The paper
- Simpson, C. D., Mattersteig, G., Martin, K., Gherghel, L., Bauer, R. E., Räder, H. J., & Müllen, K. (2004). Nanosized Molecular Propellers by Cyclodehydrogenation of Polyphenylene Dendrimers. Journal of the American Chemical Society. https://doi.org/10.1021/ja036732j
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