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A General Chemical Route to Polyaniline Nanofibers
Abstract
Uniform polyaniline nanofibers readily form using interfacial polymerization without the need for templates or functional dopants. The average diameter of the nanofibers can be tuned from 30 nm using hydrochloric acid to 120 nm using perchloric acid as observed via both scanning and transmission electron microscopy. When camphorsulfonic acid is employed, 50 nm average diameter fibers form. The measured Brunauer-Emmett-Teller surface area of the nanofibers increases as the average diameter decreases. Further characterization including molecular weight, optical spectroscopy, and electrical conductivity are presented. Interfacial polymerization is shown to be readily scalable to produce bulk quantities of nanofibers.
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Citations
Cited by
Noncarbon Support Materials for Polymer Electrolyte Membrane Fuel Cell Electrocatalysts
Wang, Y.-J., Wilkinson, D. P., & Zhang, J. (2011) · Chemical Reviews · doi:10.1021/cr100060r · Cited by 801
Nanofiber Formation in the Chemical Polymerization of Aniline: A Mechanistic Study
Huang, J., & Kaner, R. B. (2004) · Angewandte Chemie International Edition · doi:10.1002/anie.200460616 · Cited by 756
Self-citationSapurina, I., & Stejskal, J. (2008) · Polymer International · doi:10.1002/pi.2476 · Cited by 580
Electrical Switching and Bistability in Organic/Polymeric Thin Films and Memory Devices
Yang, Y., Ouyang, J., Ma, L., Tseng, R. J. ‐., & Chu, C. ‐. (2006) · Advanced Functional Materials · doi:10.1002/adfm.200500429 · Cited by 580
Polyaniline Nanofibers Prepared by Dilute Polymerization
Chiou, N. ‐., & Epstein, A. J. (2005) · Advanced Materials · doi:10.1002/adma.200401000 · Cited by 562
Metadata
- Authors
- Huang, J., & Kaner, R. B.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2003-12-30
- Volume
- 126
- Issue
- 3
- Pages
- 851-855
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2071901227
- Cited by
- 1,369
- References
- 0
- FWCI
- 46.00
- Type
- journal article
- Language
- en
- Open access
- closed
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