The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Primary Intermediates of Oxygen Photoevolution Reaction on TiO2 (Rutile) Particles, Revealed by in Situ FTIR Absorption and Photoluminescence Measurements
Abstract
Primary intermediates of oxygen photoevolution (water photooxidation) reaction at the TiO2 (rutile)/aqueous solution interface were investigated by in situ multiple internal reflection infrared (MIRIR) absorption and photoluminescence (PL) measurements. UV irradiation of TiO2 in the presence of 10 mM Fe3+ in the solution caused the appearance of a new peak at 838 cm(-1) and a shoulder at 812 cm(-1). Detailed investigations of the effects of solution pH, the presence of methanol as a hole scavenger, and isotope exchange in water (H2(16)O-->H2(18)O) on the spectra have shown that the 838- and 812-cm(-1) bands can be assigned to the O-O stretching mode of surface TiOOH and TiOOTi, respectively, produced as primary intermediates of the oxygen photoevolution reaction. The results give strong support to our previously proposed mechanism that the oxygen photoevolution is initiated by a nucleophilic attack of a H2O molecule on a photogenerated hole at a surface lattice O site, not by oxidation of surface OH group by the hole. The conclusion is supported by PL measurements. A plausible reaction scheme is proposed for the oxygen photoevolution on TiO2 (rutile) in aqueous solutions of pH less than about 12.
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Citations
Cites
Electrochemical Photolysis of Water at a Semiconductor Electrode
FUJISHIMA, A., & HONDA, K. (1972) · Nature · doi:10.1038/238037a0 · Cited by 34,169
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The surface science of titanium dioxide
Diebold, U. (2003) · Surface Science Reports · doi:10.1016/s0167-5729(02)00100-0 · Cited by 7,944
Cited by
TiO2 photocatalysis and related surface phenomena
FUJISHIMA, A., ZHANG, X., & TRYK, D. (2008) · Surface Science Reports · doi:10.1016/j.surfrep.2008.10.001 · Cited by 6,737
Surface Science Studies of the Photoactivation of TiO 2 New Photochemical Processes
Thompson, T. L., & Yates, J. T. (2006) · Chemical Reviews · doi:10.1021/cr050172k · Cited by 2,064
Time-resolved observations of water oxidation intermediates on a cobalt oxide nanoparticle catalyst
Zhang, M., de Respinis, M., & Frei, H. (2014) · Nature Chemistry · doi:10.1038/nchem.1874 · Cited by 855
Mechanistic Insight into the TiO2Photocatalytic Reactions: Design of New Photocatalysts
Tachikawa, T., Fujitsuka, M., & Majima, T. (2007) · The Journal of Physical Chemistry C · doi:10.1021/jp069005u · Cited by 668
Applications of Phosphorene and Black Phosphorus in Energy Conversion and Storage Devices
Pang, J., Bachmatiuk, A., Yin, Y., Trzebicka, B., Zhao, L., Fu, L., Mendes, R. G., Gemming, T., Liu, Z., & Rummeli, M. H. (2018) · Advanced Energy Materials · doi:10.1002/aenm.201702093 · Cited by 518
Metadata
- Authors
- Nakamura, R., & Nakato, Y.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2004-01-13
- Volume
- 126
- Issue
- 4
- Pages
- 1290-1298
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2041634101
- Cited by
- 498
- References
- 3
- FWCI
- 12.00
- Type
- journal article
- Language
- en
- Open access
- closed
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- Nakamura, R., & Nakato, Y. (2004). Primary Intermediates of Oxygen Photoevolution Reaction on TiO2 (Rutile) Particles, Revealed by in Situ FTIR Absorption and Photoluminescence Measurements. Journal of the American Chemical Society. https://doi.org/10.1021/ja0388764
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