The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Nuclear Spin Driven Quantum Tunneling of Magnetization in a New Lanthanide Single-Molecule Magnet: Bis(Phthalocyaninato)holmium Anion
Open accessAbstract
The first measurements of magnetization hysteresis loops on a diluted single crystal of [(Pc)2Ho]-.TBA+ (Pc = phthalocyaninato, TBA = tetrabutylammonium) in the subkelvin temperature range are reported. Characteristic staircase-like structure was observed, indicating the occurrence of the quantum tunneling of magnetization (QTM), which is a characteristic feature of SMMs. The quantum process in the new lanthanide SMMs is due to resonant quantum tunneling between entangled states of the electronic and nuclear spin systems, which is an essentially different mechanism from those of the known transition-metal-cluster SMMs. Evidence of the two-body quantum process was also observed for the first time in lanthanide complex systems.
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Shannon, R. D. (1976) · Acta Crystallographica Section A · doi:10.1107/s0567739476001551 · Cited by 66,145
Cited by
Lanthanide Single-Molecule Magnets
Woodruff, D. N., Winpenny, R. E. P., & Layfield, R. A. (2013) · Chemical Reviews · doi:10.1021/cr400018q · Cited by 2,781
Slow magnetization dynamics in a series of two-coordinate iron(ii) complexes
Zadrozny, J. M., Atanasov, M., Bryan, A. M., Lin, C.-Y., Rekken, B. D., Power, P. P., Neese, F., & Long, J. R. (2013) · Chem. Sci. · doi:10.1039/c2sc20801f · Cited by 579
A Family of Rare-Earth-Based Single Chain Magnets: Playing with Anisotropy
Bernot, K., Bogani, L., Caneschi, A., Gatteschi, D., & Sessoli, R. (2006) · Journal of the American Chemical Society · doi:10.1021/ja061101l · Cited by 532
Nielsen, V. R. M., & Just Sørensen, T. (2025) · Nature Communications · doi:10.1038/s41467-025-66054-7 · Cited by 5
Metadata
- Authors
- Ishikawa, N., Sugita, M., & Wernsdorfer, W.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2005-02-23
- Volume
- 127
- Issue
- 11
- Pages
- 3650-3651
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W1978071160
- Cited by
- 495
- References
- 1
- FWCI
- 11.10
- Type
- journal article
- Language
- en
- Open access
- green
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