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Electronic Properties of Single-Walled Carbon Nanotube Networks
Abstract
We present a study on the electronic behavior of films of as-prepared and purified single-walled carbon nanotubes (SWNTs) and demonstrate the important role that chemical functionalization plays in modifying their electronic properties, which in turn throws further light on the mechanism of action of SWNT-based sensors. Films of electric arc SWNTs were prepared by spraying, and optical spectroscopy was used to measure the effective film thickness. The room-temperature conductivities (sigma(RT)) of thin films deposited from as-prepared and purified SWNTs are in the range sigma(RT) = 250-400 S/cm, and the nonmetallic temperature dependence of the conductivity indicates the presence of tunneling barriers, which dominate the film conductivity. Chemical functionalization of SWNTs with octadecylamine (ODA) and poly(m-aminobenzenesulfonic acid) (PABS) significantly decreases the conductivity; sigma(RT) = 3 and 0.3 S/cm for SWNT-ODA and SWNT-PABS, respectively.
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Citations
Cited by
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Carbon supports for low-temperature fuel cell catalysts
Antolini, E. (2009) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2008.09.030 · Cited by 1,295
Carbon nanotube films for transparent and plastic electronics
Gruner, G. (2006) · Journal of Materials Chemistry · doi:10.1039/b603821m · Cited by 567
Polymer Crystallization-Driven, Periodic Patterning on Carbon Nanotubes
Li, L., Li, C. Y., & Ni, C. (2006) · Journal of the American Chemical Society · doi:10.1021/ja056923h · Cited by 375
Electrochemical sensing based on carbon nanotubes
Yáñez-Sedeño, P., Pingarrón, J. M., Riu, J., & Rius, F. X. (2010) · TrAC Trends in Analytical Chemistry · doi:10.1016/j.trac.2010.06.006 · Cited by 294
Metadata
- Authors
- Bekyarova, E., Itkis, M. E., Cabrera, N., Zhao, B., Yu, A., Gao, J., & Haddon, R. C.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2005-04-01
- Volume
- 127
- Issue
- 16
- Pages
- 5990-5995
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2011243422
- Cited by
- 404
- References
- 0
- FWCI
- 17.13
- Type
- journal article
- Language
- en
- Open access
- closed
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- Bekyarova, E., Itkis, M. E., Cabrera, N., Zhao, B., Yu, A., Gao, J., & Haddon, R. C. (2005). Electronic Properties of Single-Walled Carbon Nanotube Networks. Journal of the American Chemical Society. https://doi.org/10.1021/ja043153l
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