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Multifunctionality and Crystal Dynamics of a Highly Stable, Porous Metal−Organic Framework [Zn4O(NTB)2]
Abstract
A porous metal-organic framework [Zn(4)O(NTB)(2)].3DEF.EtOH (1), in which (3,6)-connected nets are doubly interpenetrated to generate curved three-dimensional channels, has been prepared. Framework 1 exhibits high permanent porosity (Langmuir surface area, 1121 m(2)/g; pore volume, 0.51 cm(3)/cm(3)), high thermal stability (up to 430 degrees C), high hydrogen adsorption capacity (1.9 wt % at 77 K and 1 atm), selective organic guest binding ability (K(f)()( )(): MeOH > pyridine > benzene > dodecane), and guest-dependent blue luminescence (lambda(max) depending on guest identity). Most interestingly, the framework sustains single crystallinity even at 400 degrees C and 10(-)(5) Torr, and the framework components undergo reversible dynamics, mainly rotational motion, in response to removal and rebinding of the guest molecules.
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Citations
Cited by
Metal–Organic Frameworks for Separations
Li, J.-R., Sculley, J., & Zhou, H.-C. (2012) · Chemical Reviews · doi:10.1021/cr200190s · Cited by 6,323
Luminescent metal–organic frameworks
Allendorf, M. D., Bauer, C. A., Bhakta, R. K., & Houk, R. J. T. (2009) · Chemical Society Reviews · doi:10.1039/b802352m · Cited by 4,960
Yusuf, V. F., Malek, N. I., & Kailasa, S. K. (2022) · ACS Omega · doi:10.1021/acsomega.2c05310 · Cited by 894
Ligand design for functional metal–organic frameworks
Almeida Paz, F. A., Klinowski, J., Vilela, S. M. F., Tomé, J. P. C., Cavaleiro, J. A. S., & Rocha, J. (2012) · Chem. Soc. Rev. · doi:10.1039/c1cs15055c · Cited by 855
Molecular decoding using luminescence from an entangled porous framework
Takashima, Y., Martínez, V. M., Furukawa, S., Kondo, M., Shimomura, S., Uehara, H., Nakahama, M., Sugimoto, K., & Kitagawa, S. (2011) · Nature Communications · doi:10.1038/ncomms1170 · Cited by 773
Metadata
- Authors
- Lee, E. Y., Jang, S. Y., & Suh, M. P.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2005-04-08
- Volume
- 127
- Issue
- 17
- Pages
- 6374-6381
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W1974697299
- Cited by
- 499
- References
- 0
- FWCI
- 23.17
- Type
- journal article
- Language
- en
- Open access
- closed
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- Lee, E. Y., Jang, S. Y., & Suh, M. P. (2005). Multifunctionality and Crystal Dynamics of a Highly Stable, Porous Metal−Organic Framework [Zn4O(NTB)2]. Journal of the American Chemical Society. https://doi.org/10.1021/ja043756x
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