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Rod Packings and Metal−Organic Frameworks Constructed from Rod-Shaped Secondary Building Units
Abstract
The principal structure possibilities for packing infinite rod-shaped building blocks are described. Some basic nets derived from linking simple rods (helices and ladders) are then enumerated. We demonstrate the usefulness of the concept of rod secondary building units in the design and synthesis of metal-organic frameworks (MOFs). Accordingly, we present the preparation, characterization, and crystal structures of 14 new MOFs (named MOF-69A-C and MOF-70-80) of 12 different structure types, belonging to rod packing motifs, and show how their structures are related to basic nets. The MOFs reported herein are of polytopic carboxylates and contain one of Zn, Pb, Co, Cd, Mn, or Tb. The inclusion properties of the most open members are presented as evidence that MOF structures with rod building blocks can indeed be designed to have permanent porosity and rigid architectures.
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Citations
Cited by
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Li, J.-R., Sculley, J., & Zhou, H.-C. (2012) · Chemical Reviews · doi:10.1021/cr200190s · Cited by 6,323
Carbon Dioxide Capture: Prospects for New Materials
D'Alessandro, D. M., Smit, B., & Long, J. R. (2010) · Angewandte Chemie International Edition · doi:10.1002/anie.201000431 · Cited by 4,046
Development and Evaluation of Porous Materials for Carbon Dioxide Separation and Capture
Bae, Y., & Snurr, R. Q. (2011) · Angewandte Chemie International Edition · doi:10.1002/anie.201101891 · Cited by 1,208
Metal–organic frameworks as platforms for clean energy
Li, S.-L., & Xu, Q. (2013) · Energy & Environmental Science · doi:10.1039/c3ee40507a · Cited by 970
Kökçam-Demir, Ü., Goldman, A., Esrafili, L., Gharib, M., Morsali, A., Weingart, O., & Janiak, C. (2020) · Chemical Society Reviews · doi:10.1039/c9cs00609e · Cited by 895
Metadata
- Authors
- Rosi, N. L., Kim, J., Eddaoudi, M., Chen, B., O'Keeffe, M., & Yaghi, O. M.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2005-01-13
- Volume
- 127
- Issue
- 5
- Pages
- 1504-1518
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2090264019
- Cited by
- 2,496
- References
- 0
- FWCI
- 54.68
- Type
- journal article
- Language
- en
- Open access
- closed
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- Rosi, N. L., Kim, J., Eddaoudi, M., Chen, B., O'Keeffe, M., & Yaghi, O. M. (2005). Rod Packings and Metal−Organic Frameworks Constructed from Rod-Shaped Secondary Building Units. Journal of the American Chemical Society. https://doi.org/10.1021/ja045123o
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