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Cited by 180

The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.

Two-Photon Photosensitized Production of Singlet Oxygen in Water

Frederiksen, Peter K., McIlroy, Sean P., Nielsen, Christian B., Nikolajsen, Lars, Skovsen, Esben, Jørgensen, Mikkel, Mikkelsen, Kurt V., Ogilby, Peter R.·2005·Journal of the American Chemical Society

Abstract

Singlet molecular oxygen (a(1)Delta(g)) has been produced and optically detected in time-resolved experiments upon nonlinear two-photon excitation of a photosensitizer dissolved in water. For a given sensitizer, specific functional groups that impart water solubility and that give rise to larger two-photon absorption cross sections are, in many cases, not conducive to the production of singlet oxygen in high yield. This issue involves the competing influence of intramolecular charge transfer that can be pronounced in aqueous systems; more charge transfer in the chromophore facilitates two-photon absorption but decreases the singlet oxygen yield. This phenomenon is examined in a series of porphyrins and vinyl benzenes.

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Crossref · 10.1021/ja0452020

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Metadata

Authors
Frederiksen, P. K., McIlroy, S. P., Nielsen, C. B., Nikolajsen, L., Skovsen, E., Jørgensen, M., Mikkelsen, K. V., & Ogilby, P. R.
Venue
Journal of the American Chemical Society
Published
2004-12-10
Volume
127
Issue
1
Pages
255-269
ISSN
  • 0002-7863 (ISSN-L)
  • 1520-5126
OpenAlex
W2026996455
Cited by
180
References
1
FWCI
7.71
Type
journal article
Language
en
Open access
closed

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

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