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One-Pot Synthesis of High-Quality Zinc-Blende CdS Nanocrystals
Abstract
This paper reports a one-pot synthetic method for producing CdS nanocrystals. We have demonstrated that the nanocrystal nucleation and growth stages can be automatically separated in a homogeneous system with the presence of nucleation initiators. Accelerators used for more than 70 years in rubber vulcanization (i.e., tetraethylthiuram disulfides, and 2,2'-dithiobisbenzothiazole) were found to be effective nucleation initiators for CdS nanocrystal synthesis. The as-prepared CdS nanocrystals are highly monodisperse and possess a zinc blende crystal structure. The quantum yield of the band-gap photoluminescence is up to 12% when the surface-trap emission was totally eliminated after a gentle oxidation under laboratory fluorescent light.
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Cited by
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Single-exciton optical gain in semiconductor nanocrystals
Klimov, V. I., Ivanov, S. A., Nanda, J., Achermann, M., Bezel, I., McGuire, J. A., & Piryatinski, A. (2007) · Nature · doi:10.1038/nature05839 · Cited by 992
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Bao, J., & Bawendi, M. G. (2015) · Nature · doi:10.1038/nature14576 · Cited by 735
Metadata
- Authors
- Cao, Y. C., & Wang, J.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2004-10-15
- Volume
- 126
- Issue
- 44
- Pages
- 14336-14337
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2046822153
- Cited by
- 366
- References
- 0
- FWCI
- 10.62
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: One-Pot Synthesis of High-Quality Zinc-Blende CdS Nanocrystals. https://app.cochat.ai/papers/10.1021/ja0459678
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- Cao, Y. C., & Wang, J. (2004). One-Pot Synthesis of High-Quality Zinc-Blende CdS Nanocrystals. Journal of the American Chemical Society. https://doi.org/10.1021/ja0459678
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
