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Cited by 363

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Photochromic and Luminescence Switching Properties of a Versatile Diarylethene-Containing 1,10-Phenanthroline Ligand and Its Rhenium(I) Complex

Yam, Vivian Wing-Wah, Ko, Chi-Chiu, Zhu, Nianyong·2004·Journal of the American Chemical Society

Abstract

A versatile bis(2,5-dimethyl-3-thienyl)-1,10-phenanthroline photochromic ligand has been successfully synthesized via a Suzuki cross-coupling reaction. The excitation wavelength for photochromic reaction of the dithienylphenanthroline could be extended from lambda </= 340 nm in the UV region to ca. 480 nm in the visible region, corresponding to the MLCT excitation, through the incorporation into the rhenium(I) tricarbonyl system. Reversible switching of the emissive state by the photochromic reaction has also been demonstrated.

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Authors
Yam, V. W.-W., Ko, C.-C., & Zhu, N.
Venue
Journal of the American Chemical Society
Published
2004-09-18
Volume
126
Issue
40
Pages
12734-12735
ISSN
  • 0002-7863 (ISSN-L)
  • 1520-5126
OpenAlex
W2003928423
Cited by
363
References
0
FWCI
7.71
Type
journal article
Language
en
Open access
closed

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