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Cited by 338

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Carbon Nanotubes with Covalently Linked Porphyrin Antennae: Photoinduced Electron Transfer

Baskaran, Durairaj, Mays, Jimmy W., Zhang, X. Peter, Bratcher, Matthew S.·2005·Journal of the American Chemical Society

Abstract

Single- and multiwalled carbon nanotubes have been covalently functionalized with free-base porphyrin. The quantity of porphyrin linked to the surface was determined from thermogravimetric and UV-vis analysis. A reversible protonation equilibrium between the attached porphyrin and the residual acid groups of the carbon nanotubes has been identified. Steady-state fluorescence emission spectrum of the solutions of porphyrin-linked carbon nanotubes shows that the porphyrins act as energy absorbing and electron transferring antennae, and the carbon nanotubes act as efficient electron acceptors. The porphyrin-linked carbon nanotubes show 95-100% emission quenching, indicating a fast photoinduced electron transfer.

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Authors
Baskaran, D., Mays, J. W., Zhang, X. P., & Bratcher, M. S.
Venue
Journal of the American Chemical Society
Published
2005-04-20
Volume
127
Issue
19
Pages
6916-6917
ISSN
  • 0002-7863 (ISSN-L)
  • 1520-5126
OpenAlex
W2089646493
Cited by
338
References
0
FWCI
15.72
Type
journal article
Language
en
Open access
closed

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.