The DOI matches its Crossref record.
Oxidative C−H Activation/C−C Bond Forming Reactions: Synthetic Scope and Mechanistic Insights
Abstract
This paper describes a new palladium-catalyzed method for C-H activation/carbon-carbon bond formation with hypervalent iodine arylating agents. This transformation has been applied to a variety of arene and benzylic substrates containing different directing groups (pyridines, quinolines, oxazolidinones, and amides) and proceeds with high levels of regiocontrol. Mechanistic experiments provide preliminary evidence in support of an unusual mechanism for this transformation involving a Pd(II)/Pd(IV) catalytic cycle.
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Citations
Cited by
Prier, C. K., Rankic, D. A., & MacMillan, D. W. C. (2013) · Chemical Reviews · doi:10.1021/cr300503r · Cited by 9,590
Metadata
- Authors
- Kalyani, D., Deprez, N. R., Desai, L. V., & Sanford, M. S.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2005-05-03
- Volume
- 127
- Issue
- 20
- Pages
- 7330-7331
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2071053863
- Cited by
- 796
- References
- 0
- FWCI
- 27.59
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Oxidative C−H Activation/C−C Bond Forming Reactions: Synthetic Scope and Mechanistic Insights. https://app.cochat.ai/papers/10.1021/ja051402f
- The paper
- Kalyani, D., Deprez, N. R., Desai, L. V., & Sanford, M. S. (2005). Oxidative C−H Activation/C−C Bond Forming Reactions: Synthetic Scope and Mechanistic Insights. Journal of the American Chemical Society. https://doi.org/10.1021/ja051402f
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
