The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Size-Specific Catalytic Activity of Polymer-Stabilized Gold Nanoclusters for Aerobic Alcohol Oxidation in Water
Abstract
Gold nanoclusters (phi = 1.3 nm) stabilized by poly(N-vinyl-2-pyrrolidone) (Au:PVP NCs) readily oxidize benzylic alcohols to the corresponding aldehydes and/or carboxylic acids under ambient temperature in water. Kinetic measurement revealed that smaller Au:PVP NCs exhibit higher catalytic activity than larger (9.5 nm) homologues and, more surprisingly, than Pd:PVP NCs of comparable size (1.5 and 2.2 nm). On the basis of the marked difference in the kinetic isotope effect and activation energy between Au:PVP and Pd:PVP NCs, a reaction mechanism for alcohol oxidation catalyzed by Au:PVP NCs is proposed in which a superoxo-like molecular oxygen species adsorbed on the surface of the small Au NCs abstracts a hydrogen atom from the alkoxide.
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Citations
Cites
Charging Effects on Bonding and Catalyzed Oxidation of CO on Au 8 Clusters on MgO
Yoon, B., Häkkinen, H., Landman, U., Wörz, A. S., Antonietti, J.-M., Abbet, S., Judai, K., & Heiz, U. (2005) · Science · doi:10.1126/science.1104168 · Cited by 1,430
Cited by
Hashmi, A. S. K., & Hutchings, G. J. (2006) · Angewandte Chemie International Edition · doi:10.1002/anie.200602454 · Cited by 3,423
Gold-Catalyzed Organic Reactions
Hashmi, A. S. K. (2007) · Chemical Reviews · doi:10.1021/cr000436x · Cited by 3,271
Quantum sized, thiolate-protected gold nanoclusters
Jin, R. (2010) · Nanoscale · doi:10.1039/b9nr00160c · Cited by 1,442
Selective oxidation of alcohols and aldehydes over supported metal nanoparticles
Davis, S. E., Ide, M. S., & Davis, R. J. (2013) · Green Chem. · doi:10.1039/c2gc36441g · Cited by 802
Panigrahi, S., Basu, S., Praharaj, S., Pande, S., Jana, S., Pal, A., Ghosh, S. K., & Pal, T. (2007) · The Journal of Physical Chemistry C · doi:10.1021/jp067554u · Cited by 786
Metadata
- Authors
- Tsunoyama, H., Sakurai, H., Negishi, Y., & Tsukuda, T.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2005-06-14
- Volume
- 127
- Issue
- 26
- Pages
- 9374-9375
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2036255100
- Cited by
- 880
- References
- 1
- FWCI
- 19.95
- Type
- journal article
- Language
- en
- Open access
- closed
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- Tsunoyama, H., Sakurai, H., Negishi, Y., & Tsukuda, T. (2005). Size-Specific Catalytic Activity of Polymer-Stabilized Gold Nanoclusters for Aerobic Alcohol Oxidation in Water. Journal of the American Chemical Society. https://doi.org/10.1021/ja052161e
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
