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Potential Dependent Organization of Water at the Electrified Metal−Liquid Interface
Abstract
In situ infrared visible sum frequency generation spectroscopy (SFG) is used to examine the structure of water at the Ag-water interface in NaF and KF electrolyte solutions. Water is observed in environments associated with both the electrode surface and the diffuse double layer. Peaks are observed that are correlated with low-order water, water interacting with electrolyte ions, specifically adsorbed water to the electrode surface, and hydronium. Spectra obtained from a thiol-modified Ag surface enabled discrimination between surface-bound water and that in the double layer. The water organization is dependent on applied potential, with the observed intensities for specifically adsorbed and ion solvating water diminishing near the pzc.
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Cited by
In situ probing electrified interfacial water structures at atomically flat surfaces
Li, C.-Y., Le, J.-B., Wang, Y.-H., Chen, S., Yang, Z.-L., Li, J.-F., Cheng, J., & Tian, Z.-Q. (2019) · Nature Materials · doi:10.1038/s41563-019-0356-x · Cited by 789
Waegele, M. M., Gunathunge, C. M., Li, J., & Li, X. (2019) · The Journal of Chemical Physics · doi:10.1063/1.5124878 · Cited by 423
On the importance of the electric double layer structure in aqueous electrocatalysis
Shin, S.-J., Kim, D. H., Bae, G., Ringe, S., Choi, H., Lim, H.-K., Choi, C. H., & Kim, H. (2022) · Nature Communications · doi:10.1038/s41467-021-27909-x · Cited by 325
Osawa, M., Tsushima, M., Mogami, H., Samjeské, G., & Yamakata, A. (2008) · The Journal of Physical Chemistry C · doi:10.1021/jp710386g · Cited by 324
Ab Initio Simulations of Water/Metal Interfaces
Groß, A., & Sakong, S. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.1c00679 · Cited by 303
Metadata
- Authors
- Schultz, Z. D., Shaw, S. K., & Gewirth, A. A.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2005-10-22
- Volume
- 127
- Issue
- 45
- Pages
- 15916-15922
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W1979568060
- Cited by
- 168
- References
- 0
- FWCI
- 3.48
- Type
- journal article
- Language
- en
- Open access
- closed
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- Schultz, Z. D., Shaw, S. K., & Gewirth, A. A. (2005). Potential Dependent Organization of Water at the Electrified Metal−Liquid Interface. Journal of the American Chemical Society. https://doi.org/10.1021/ja0543393
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