The DOI matches its Crossref record; 7 of the 7 references it cites were found in a registry or an index.
The Cucurbit[n]uril Family: Prime Components for Self-Sorting Systems
Abstract
We determined the values of Ka for a wide range of host-guest complexes of cucurbit[n]uril (CB[n]), where n = 6-8, using 1H NMR competition experiments referenced to absolute binding constants measured by UV/vis titration. We find that the larger homologues--CB[7] and CB[8]--individually maintain the size, shape, and functional group selectivity that typifies the recognition behavior of CB[6]. The cavity of CB[7] is found to effectively host trimethylsilyl groups. Remarkably, the values of Ka for the interaction of CB[7] with adamantane derivatives 22-24 exceeds 10(12) M(-1)! The high levels of selectivity observed for each CB[n] individually is also observed for the CB[n] family collectively. That is, the selectivities of CB[6], CB[7], and CB[8] toward a common guest can be remarkably large. For example, guests 1, 3, and 11 prefer CB[8] relative to CB[7] by factors greater than 10(7), 10(6), and 3000, respectively. Conversely, guests 23 and 24 prefer CB[7] relative to CB[8] by factors greater than 5100 and 990, respectively. The high levels of selectivity observed individually and collectively for the CB[n] family renders them prime components for the preparation of functional biomimetic self-sorting systems.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Data Reduction and Error Analysis for the Physical Sciences
Bevington, P. R., Robinson, D. K., Blair, J. M., Mallinckrodt, A. J., & McKay, S. (1993) · Computers in Physics · doi:10.1063/1.4823194 · Cited by 14,824
Lagona, J., Mukhopadhyay, P., Chakrabarti, S., & Isaacs, L. (2005) · Angewandte Chemie International Edition · doi:10.1002/anie.200460675 · Cited by 2,444
Self-citationCohen, Y., Avram, L., & Frish, L. (2005) · Angewandte Chemie International Edition · doi:10.1002/anie.200300637 · Cited by 1,122
(1915) · Journal of Education · doi:10.1177/002205741508200834 · Cited by 616
Molecular Necklace: Quantitative Self-Assembly of a Cyclic Oligorotaxane from Nine Molecules
Whang, D., Park, K., Heo, J., Ashton, P. R., & Kim, K. (1998) · Journal of the American Chemical Society · doi:10.1021/ja980029r · Cited by 217
Nishimura, S., Niikura, K., Kurogochi, M., Matsushita, T., Fumoto, M., Hinou, H., Kamitani, R., Nakagawa, H., Deguchi, K., Miura, N., et al. (2005) · Angewandte Chemie International Edition · doi:10.1002/anie.200461685 · Cited by 169
McCurdy, A., Jimenez, L. S., Stauffer, D. A., & Dougherty, D. A. (1992) · Journal of the American Chemical Society · doi:10.1021/ja00052a031 · Cited by 148
Cited by
Xia, D., Wang, P., Ji, X., Khashab, N. M., Sessler, J. L., & Huang, F. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.9b00839 · Cited by 734
Ma, D., Hettiarachchi, G., Nguyen, D., Zhang, B., Wittenberg, J. B., Zavalij, P. Y., Briken, V., & Isaacs, L. (2012) · Nature Chemistry · doi:10.1038/nchem.1326 · Cited by 451
Self-citationCrystallization and near-infrared emission from host–guest based supramolecular polymers
Yin, W., Meng, L., Yu, T., Chen, J., Hu, R., Yang, G., Zeng, Y., & Li, Y. (2021) · New Journal of Chemistry · doi:10.1039/d1nj01398j · Cited by 2
Metadata
- Authors
- Liu, S., Ruspic, C., Mukhopadhyay, P., Chakrabarti, S., Zavalij, P. Y., & Isaacs, L.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2005-10-21
- Volume
- 127
- Issue
- 45
- Pages
- 15959-15967
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2091068412
- Cited by
- 854
- References
- 7
- FWCI
- 14.09
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: The Cucurbit[n]uril Family: Prime Components for Self-Sorting Systems. https://app.cochat.ai/papers/10.1021/ja055013x
- The paper
- Liu, S., Ruspic, C., Mukhopadhyay, P., Chakrabarti, S., Zavalij, P. Y., & Isaacs, L. (2005). The Cucurbit[n]uril Family: Prime Components for Self-Sorting Systems. Journal of the American Chemical Society. https://doi.org/10.1021/ja055013x
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
