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Cited by 294

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Microemulsion-Templated Synthesis of Carbon Nanotube-Supported Pd and Rh Nanoparticles for Catalytic Applications

Yoon, Byunghoon, Wai, Chien M.·2005·Journal of the American Chemical Society

Abstract

Palladium, rhodium, and bimetallic Pd/Rh nanoparticles synthesized in a water-in-hexane microemulsion can be deposited directly on surfaces of functionalized multiwalled carbon nanotubes with high yields. The CNT-supported Pd nanoparticles are active catalysts for hydrogenation of olefins, for carbon-carbon bond formation, and for carbon-oxygen bond cleavage reactions. The CNT-supported Rh nanoparticles are active catalysts for hydrogenation of arenes, and the CNT-supported bimetallic Pd/Rh nanoparticles show an unusually high catalytic activity for hydrogenation of anthracene. This simple and novel synthetic technique for making CNT-supported monometallic and bimetallic nanoparticles may have a wide range of catalytic applications for chemical syntheses.

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Metadata

Authors
Yoon, B., & Wai, C. M.
Venue
Journal of the American Chemical Society
Published
2005-11-16
Volume
127
Issue
49
Pages
17174-17175
ISSN
  • 0002-7863 (ISSN-L)
  • 1520-5126
OpenAlex
W2051940566
Cited by
294
References
0
FWCI
12.90
Type
journal article
Language
en
Open access
closed

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