The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Kinetically Controlled Synthesis of Triangular and Hexagonal Nanoplates of Palladium and Their SPR/SERS Properties
Abstract
The rapid reduction of Na(2)PdCl(4) by ethylene glycol in the presence of poly(vinyl pyrrolidone) (PVP) has recently been demonstrated as a convenient method of generating Pd cubooctahedra and twinned nanoparticles. Here we describe a new procedure where Pd triangular or hexagonal nanoplates could be selectively synthesized by manipulating the reduction kinetics of the polyol process. More specifically, the reduction rate was substantially reduced through the introduction of Fe(III) species and the O(2)/Cl(-) pair, two wet etchants for Pd(0). The etching power of the O(2)/Cl(-) pair could be further enhanced by adding an acid to lower the pH of the reaction solution. Unlike the previously reported synthesis of Ag and Au nanoplates, light was found to have no indispensable role in the formation of Pd nanoplates. Both triangular and hexagonal nanoplates of Pd exhibited surface plasmon resonance (SPR) peaks in the visible region, and their positions matched with the results of discrete dipole approximation (DDA) calculation. Thanks to their sharp corners and edges, these Pd nanoplates could serve as active substrates for surface-enhanced Raman scattering (SERS).
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Cites
Monodisperse FePt Nanoparticles and Ferromagnetic FePt Nanocrystal Superlattices
Sun, S., Murray, C. B., Weller, D., Folks, L., & Moser, A. (2000) · Science · doi:10.1126/science.287.5460.1989 · Cited by 6,137
Transmission Electron Microscopy of Shape-Controlled Nanocrystals and Their Assemblies
Wang, Z. L. (2000) · The Journal of Physical Chemistry B · doi:10.1021/jp993593c · Cited by 2,137
Preparing Monodisperse Metal Powders in Micrometer and Submicrometer Sizes by the Polyol Process
Fievet, F., Lagier, J. P., & Figlarz, M. (1989) · MRS Bulletin · doi:10.1557/s0883769400060930 · Cited by 585
Cited by
Shape‐Controlled Synthesis of Metal Nanocrystals: Simple Chemistry Meets Complex Physics?
Xia, Y., Xiong, Y., Lim, B., & Skrabalak, S. E. (2009) · Angewandte Chemie International Edition · doi:10.1002/anie.200802248 · Cited by 5,702
Self-citationNanostructured Pt-alloy electrocatalysts for PEM fuel cell oxygen reduction reaction
Bing, Y., Liu, H., Zhang, L., Ghosh, D., & Zhang, J. (2010) · Chemical Society Reviews · doi:10.1039/b912552c · Cited by 1,154
Murray, W. A., & Barnes, W. L. (2007) · Advanced Materials · doi:10.1002/adma.200700678 · Cited by 837
Shape-Controlled Synthesis of Pd Nanocrystals and Their Catalytic Applications
Zhang, H., Jin, M., Xiong, Y., Lim, B., & Xia, Y. (2013) · Accounts of Chemical Research · doi:10.1021/ar300209w · Cited by 644
Self-citationXiong, Y., Washio, I., Chen, J., Cai, H., Li, Z.-Y., & Xia, Y. (2006) · Langmuir · doi:10.1021/la061323x · Cited by 640
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Metadata
- Authors
- Xiong, Y., McLellan, J. M., Chen, J., Yin, Y., Li, Z.-Y., & Xia, Y.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2005-11-10
- Volume
- 127
- Issue
- 48
- Pages
- 17118-17127
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2025450830
- Cited by
- 669
- References
- 3
- FWCI
- 21.82
- Type
- journal article
- Language
- en
- Open access
- closed
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- Xiong, Y., McLellan, J. M., Chen, J., Yin, Y., Li, Z.-Y., & Xia, Y. (2005). Kinetically Controlled Synthesis of Triangular and Hexagonal Nanoplates of Palladium and Their SPR/SERS Properties. Journal of the American Chemical Society. https://doi.org/10.1021/ja056498s
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