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Efficient Homogeneous Catalysis in the Reduction of CO2 to CO
Abstract
The well-defined copper(I) boryl complex [(IPr)Cu(Bpin)] [where IPr = 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene, and pin = pinacolate: 2,3-dimethyl-2,3-butanediolate] deoxygenates CO2 rapidly and quantitatively, affording CO and the borate complex [(IPr)Cu(OBpin)]. The boryl may be regenerated by treatment with the diboron compound pinB-Bpin, giving the stable byproduct pinB-O-Bpin. The use of a copper(I) alkoxide precatalyst and stoichiometric diboron reagent results in catalytic reduction of CO2, with high turnover numbers (1000 per Cu) and frequencies (100 per Cu in 1 h) depending on supporting ligand and reaction conditions.
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Cited by
Semiconductor Quantum Dots: An Emerging Candidate for CO2 Photoreduction
Wu, H., Li, X., Tung, C., & Wu, L. (2019) · Advanced Materials · doi:10.1002/adma.201900709 · Cited by 486
Metal centers in the anaerobic microbial metabolism of CO and CO2
Bender, G., Pierce, E., Hill, J. A., Darty, J. E., & Ragsdale, S. W. (2011) · Metallomics · doi:10.1039/c1mt00042j · Cited by 68
Metadata
- Authors
- Laitar, D. S., Müller, P., & Sadighi, J. P.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2005-11-18
- Volume
- 127
- Issue
- 49
- Pages
- 17196-17197
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W1998085580
- Cited by
- 663
- References
- 0
- FWCI
- 20.39
- Type
- journal article
- Language
- en
- Open access
- closed
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- Laitar, D. S., Müller, P., & Sadighi, J. P. (2005). Efficient Homogeneous Catalysis in the Reduction of CO2 to CO. Journal of the American Chemical Society. https://doi.org/10.1021/ja0566679
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