The DOI matches its Crossref record; 40 of the 40 references it cites were found in a registry or an index.
Unusual Hydrogen Bonding in Water-Filled Carbon Nanotubes
Abstract
We present the first experimental vibrational spectroscopy study providing direct evidence of a water phase inside single-walled carbon nanotubes that exhibits an unusual form of hydrogen-bonding due to confinement. Water adopts a stacked-ring structure inside nanotubes, forming intra- and inter-ring hydrogen bonds. The intra-ring hydrogen bonds are bulk-like while the inter-ring hydrogen bonds are relatively weak, having a distorted geometry that gives rise to a distinct OH stretching mode. The experimentally observed infrared mode at 3507 cm(-1) is assigned to vibrations of the inter-ring OH-groups based on detailed atomic-level modeling. The direct observation of unusual hydrogen bonding in nanotubes has potential implications for water in other highly confined systems, such as biological channels and nanoporous media.
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Cited by
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Metadata
- Authors
- Byl, O., Liu, J.-C., Wang, Y., Yim, W.-L., Johnson, J. K., & Yates, J. T.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2006-08-29
- Volume
- 128
- Issue
- 37
- Pages
- 12090-12097
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2084362915
- Cited by
- 294
- References
- 40
- FWCI
- 13.89
- Type
- journal article
- Language
- en
- Open access
- closed
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