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Cited by 294

The DOI matches its Crossref record; 40 of the 40 references it cites were found in a registry or an index.

Unusual Hydrogen Bonding in Water-Filled Carbon Nanotubes

Byl, Oleg, Liu, Jin-Chen, Wang, Yang, Yim, Wai-Leung, Johnson, J. Karl, Yates, John T.·2006·Journal of the American Chemical Society

Abstract

We present the first experimental vibrational spectroscopy study providing direct evidence of a water phase inside single-walled carbon nanotubes that exhibits an unusual form of hydrogen-bonding due to confinement. Water adopts a stacked-ring structure inside nanotubes, forming intra- and inter-ring hydrogen bonds. The intra-ring hydrogen bonds are bulk-like while the inter-ring hydrogen bonds are relatively weak, having a distorted geometry that gives rise to a distinct OH stretching mode. The experimentally observed infrared mode at 3507 cm(-1) is assigned to vibrations of the inter-ring OH-groups based on detailed atomic-level modeling. The direct observation of unusual hydrogen bonding in nanotubes has potential implications for water in other highly confined systems, such as biological channels and nanoporous media.

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Metadata

Authors
Byl, O., Liu, J.-C., Wang, Y., Yim, W.-L., Johnson, J. K., & Yates, J. T.
Venue
Journal of the American Chemical Society
Published
2006-08-29
Volume
128
Issue
37
Pages
12090-12097
ISSN
  • 0002-7863 (ISSN-L)
  • 1520-5126
OpenAlex
W2084362915
Cited by
294
References
40
FWCI
13.89
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Unusual Hydrogen Bonding in Water-Filled Carbon Nanotubes. https://app.cochat.ai/papers/10.1021/ja057856u
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Byl, O., Liu, J.-C., Wang, Y., Yim, W.-L., Johnson, J. K., & Yates, J. T. (2006). Unusual Hydrogen Bonding in Water-Filled Carbon Nanotubes. Journal of the American Chemical Society. https://doi.org/10.1021/ja057856u

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

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