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Preparation of Highly Dispersed Core/Shell-type Titania Nanocapsules Containing a Single Ag Nanoparticle
Abstract
Core/shell-type titania nanocapsules containing a single Ag nanoparticle were prepared. Ag nanoparticles were prepared using the reduction of silver nitrate with hydrazine in the presence of cetyltrimethylammonium bromide (CTAB) as protective agent. The sol-gel reaction of titanium tetraisopropoxide (TTIP) was used to prepare core/shell-type titania nanocapsules with CTAB-coated Ag nanoparticles as the core. TEM observations revealed that the size of the core (Ag particle) and the thickness of the shell (titania) of the core/shell particles obtained are about 10 nm and 5-10 nm, respectively. In addition, the nanocapsules were found to be dispersed in the medium as individual particles without aggregation. Moreover, titania coating caused the surface plasmon absorption of Ag nanoparticles to shift toward the longer wavelength side.
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Cites
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Burda, C., Chen, X., Narayanan, R., & El-Sayed, M. A. (2005) · Chemical Reviews · doi:10.1021/cr030063a · Cited by 7,230
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Carbone, L., & Cozzoli, P. D. (2010) · Nano Today · doi:10.1016/j.nantod.2010.08.006 · Cited by 691
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Dahl, M., Liu, Y., & Yin, Y. (2014) · Chemical Reviews · doi:10.1021/cr400634p · Cited by 687
Synthesis of M@TiO2 (M = Au, Pd, Pt) Core–Shell Nanocomposites with Tunable Photoreactivity
Zhang, N., Liu, S., Fu, X., & Xu, Y.-J. (2011) · The Journal of Physical Chemistry C · doi:10.1021/jp2009989 · Cited by 594
Abdelgawad, A. M., Hudson, S. M., & Rojas, O. J. (2014) · Carbohydrate Polymers · doi:10.1016/j.carbpol.2012.12.043 · Cited by 553
Enhancement of visible photocatalytic activity via Ag@C3N4 core–shell plasmonic composite
Bai, X., Zong, R., Li, C., Liu, D., Liu, Y., & Zhu, Y. (2014) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2013.08.007 · Cited by 512
Mesoporous Anatase Titania Hollow Nanostructures though Silica‐Protected Calcination
Joo, J. B., Zhang, Q., Lee, I., Dahl, M., Zaera, F., & Yin, Y. (2012) · Advanced Functional Materials · doi:10.1002/adfm.201101927 · Cited by 433
Nanointerface Chemistry: Lattice-Mismatch-Directed Synthesis and Application of Hybrid Nanocrystals
Liu, J., & Zhang, J. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.9b00443 · Cited by 423
Metadata
- Authors
- Sakai, H., Kanda, T., Shibata, H., Ohkubo, T., & Abe, M.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2006-03-23
- Volume
- 128
- Issue
- 15
- Pages
- 4944-4945
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2092024414
- Cited by
- 206
- References
- 1
- FWCI
- 5.76
- Type
- journal article
- Language
- en
- Open access
- closed
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