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Colloidal HgTe Nanocrystals with Widely Tunable Narrow Band Gap Energies: From Telecommunications to Molecular Vibrations

Kovalenko, Maksym V., Kaufmann, Erich, Pachinger, Dietmar, Roither, Jürgen, Huber, Martin, Stangl, Julian, Hesser, Günter, Schäffler, Friedrich, Heiss, Wolfgang·2006·Journal of the American Chemical Society

Abstract

A convenient, aqueous-based synthesis of stable HgTe nanocrystals with widely size-tunable room temperature emission between wavelengths of 1.2 to 3.7 mum is demonstrated. By the choice of the thiols, applied as stabilizers, we optimized the growth dynamics, the luminescence quantum yields (up to 40%), and a ligand-exchange procedure, required to transfer the nanocrystals from water to nonpolar organic solvents. The latter is greatly improved and facilitated by the use of mercaptoethylamine as initial stabilizer. The possibility to tune the HgTe nanocrystal sizes from 3 to 12 nm and to control their surface functionalities (hydrophobic and hydrophilic) makes them very promising for the development of infrared optical devices, emitting in the wavelength region between the telecommunications and the molecular vibrations.

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Metadata

Authors
Kovalenko, M. V., Kaufmann, E., Pachinger, D., Roither, J., Huber, M., Stangl, J., Hesser, G., Schäffler, F., & Heiss, W.
Venue
Journal of the American Chemical Society
Published
2006-02-22
Volume
128
Issue
11
Pages
3516-3517
ISSN
  • 0002-7863 (ISSN-L)
  • 1520-5126
OpenAlex
W2068732553
Cited by
216
References
0
FWCI
5.64
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Colloidal HgTe Nanocrystals with Widely Tunable Narrow Band Gap Energies: From Telecommunications to Molecular Vibrations. https://app.cochat.ai/papers/10.1021/ja058440j
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Kovalenko, M. V., Kaufmann, E., Pachinger, D., Roither, J., Huber, M., Stangl, J., Hesser, G., Schäffler, F., & Heiss, W. (2006). Colloidal HgTe Nanocrystals with Widely Tunable Narrow Band Gap Energies: From Telecommunications to Molecular Vibrations. Journal of the American Chemical Society. https://doi.org/10.1021/ja058440j

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

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