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An Efficient Route to Well-Defined Macrocyclic Polymers via “Click” Cyclization
Abstract
Polystyrene macrocycles have been prepared from ATRP precursors by modification of the terminal bromide to an azide, followed by "click" cyclization with a pendant alkyne from the initiator. This route offers exceptional control over the size and polydispersity of the macrocyclic polymers, as well as providing tolerance to a number of functional groups.
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Citations
Cited by
Controlled/living radical polymerization: Features, developments, and perspectives
Braunecker, W. A., & Matyjaszewski, K. (2007) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2006.11.002 · Cited by 3,202
The growing applications of click chemistry
Moses, J. E., & Moorhouse, A. D. (2007) · Chem. Soc. Rev. · doi:10.1039/b613014n · Cited by 2,367
Ouchi, M., Terashima, T., & Sawamoto, M. (2009) · Chemical Reviews · doi:10.1021/cr900234b · Cited by 1,257
Marrying click chemistry with polymerization: expanding the scope of polymeric materials
Golas, P. L., & Matyjaszewski, K. (2010) · Chem. Soc. Rev. · doi:10.1039/b901978m · Cited by 863
“Click”‐Chemistry in Polymer and Material Science: the Update
Binder, W. H. (2008) · Macromolecular Rapid Communications · doi:10.1002/marc.200800332 · Cited by 567
Metadata
- Authors
- Laurent, B. A., & Grayson, S. M.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2006-03-14
- Volume
- 128
- Issue
- 13
- Pages
- 4238-4239
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2023438921
- Cited by
- 700
- References
- 0
- FWCI
- 33.50
- Type
- journal article
- Language
- en
- Open access
- closed
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- Laurent, B. A., & Grayson, S. M. (2006). An Efficient Route to Well-Defined Macrocyclic Polymers via “Click” Cyclization. Journal of the American Chemical Society. https://doi.org/10.1021/ja0585836
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
