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Synthesis of Metal Nanoparticles Stabilized by Metal−Carbon Bonds

Mirkhalaf, Fakhradin, Paprotny, Jerzy, Schiffrin, David J.·2006·Journal of the American Chemical Society

Abstract

A new method for the preparation of metal nanoparticles in organic media is proposed. This is based on the formation of metal-carbon bonds after reduction of the corresponding diazonium derivative of the capping ligand. The particles are very stable due to the strong metal-ligand covalent bond, and the proposed method appears to be an alternative for the preparation of monolayer-protected metal nanoparticles when the formation of metal-sulfur or metal-nitrogen bonds needs to be avoided.

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Metadata

Authors
Mirkhalaf, F., Paprotny, J., & Schiffrin, D. J.
Venue
Journal of the American Chemical Society
Published
2006-05-17
Volume
128
Issue
23
Pages
7400-7401
ISSN
  • 0002-7863 (ISSN-L)
  • 1520-5126
OpenAlex
W2034693967
Cited by
195
References
0
FWCI
7.35
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Synthesis of Metal Nanoparticles Stabilized by Metal−Carbon Bonds. https://app.cochat.ai/papers/10.1021/ja058687g
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Mirkhalaf, F., Paprotny, J., & Schiffrin, D. J. (2006). Synthesis of Metal Nanoparticles Stabilized by Metal−Carbon Bonds. Journal of the American Chemical Society. https://doi.org/10.1021/ja058687g

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.