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Cited by 788

The DOI matches its Crossref record; 8 of the 8 references it cites were found in a registry or an index.

Translucent Thin Film Fe2O3 Photoanodes for Efficient Water Splitting by Sunlight: Nanostructure-Directing Effect of Si-Doping

Cesar, Ilkay, Kay, Andreas, Gonzalez Martinez, José A., Grätzel, Michael·2006·Journal of the American Chemical Society

Abstract

Thin, silicon-doped nanocrystalline alpha-Fe2O3 films have been deposited on F-doped SnO2 substrates by ultrasonic spray pyrolysis and chemical vapor deposition at atmospheric pressure. The photocatalytic activity of these films with regard to photoelectrochemical water oxidation was measured at pH 13.6 under simulated AM 1.5 global sunlight. The photoanodes prepared by USP and APCVD gave 1.17 and 1.45 mA/cm2, respectively, at 1.23 V vs RHE. The morphology of the alpha-Fe2O3 was strongly influenced by the silicon doping, decreasing the feature size of the mesoscopic film. The silicon-doped alpha-Fe2O3 nano-leaflets show a preferred orientation with the (001) basal plane normal to the substrate. The best performing photoanode would yield a solar-to-chemical conversion efficiency of 2.1% in a tandem device using two dye-sensitized solar cells in series.

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Metadata

Authors
Cesar, I., Kay, A., Gonzalez Martinez, J. A., & Grätzel, M.
Venue
Journal of the American Chemical Society
Published
2006-03-18
Volume
128
Issue
14
Pages
4582-4583
ISSN
  • 0002-7863 (ISSN-L)
  • 1520-5126
OpenAlex
W1968488118
Cited by
788
References
8
FWCI
20.72
Type
journal article
Language
en
Open access
closed

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

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