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Synthesis of FePt Nanocubes and Their Oriented Self-Assembly
Abstract
Monodisperse FePt nanocubes are synthesized at 205 degrees C by controlling decomposition of Fe(CO)5 and reduction of Pt(acac)2 and addition sequence of oleic acid and oleylamine. Different from the assembly of the sphere-like FePt nanoparticles, which shows 3D random structure orientation, self-assembly of the FePt nanocubes leads to a superlattice array with each FePt cube exhibiting (100) texture. Thermal annealing converts the chemically disordered fcc FePt to chemically ordered fct FePt, and the annealed assembly shows a strong (001) texture in the directions both parallel and perpendicular to the substrate. This shape-controlled synthesis and self-assembly offers a promising approach to fabrication of magnetically aligned FePt nanocrystal arrays for high density information storage and high performance permanent magnet applications.
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Cited by
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Peng, Z., & Yang, H. (2009) · Nano Today · doi:10.1016/j.nantod.2008.10.010 · Cited by 1,085
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Guo, S., Zhang, S., & Sun, S. (2013) · Angewandte Chemie International Edition · doi:10.1002/anie.201207186 · Cited by 994
Self-citationSynthesis and Oxygen Reduction Activity of Shape-Controlled Pt3Ni Nanopolyhedra
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Metadata
- Authors
- Chen, M., Kim, J., Liu, J. P., Fan, H., & Sun, S.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2006-05-13
- Volume
- 128
- Issue
- 22
- Pages
- 7132-7133
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2080102439
- Cited by
- 319
- References
- 0
- FWCI
- 13.52
- Type
- journal article
- Language
- en
- Open access
- closed
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- Chen, M., Kim, J., Liu, J. P., Fan, H., & Sun, S. (2006). Synthesis of FePt Nanocubes and Their Oriented Self-Assembly. Journal of the American Chemical Society. https://doi.org/10.1021/ja061704x
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