The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Hydrogen- and Fluorine-Bridged Disilyl Cations and Their Use in Catalytic C−F Activation
Abstract
The hydrogen-bridged disilyl cation 6 with an 1,8-naphthalenediyl backbone was synthesized and was characterized by NMR spectroscopy and X-ray crystallography, supported by quantum mechanical computations. The SiHSi linkage is symmetrical, corresponding to a single minimum potential, and the structural parameters are in agreement with the presence of a two electron-three center bond in 6. Treatment of disilyl cation 6 with alkyl fluorides yields the disilylfluoronium ion 10. The SiFSi group in the disilyl fluoronium ion 10 is symmetrical with an average SiF bond length of 175.9(8) and a bent angle beta = 130 degrees . Both cations catalyze the hydrodefluorination reaction of alkyl and benzyl fluorides to give alkanes.
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Cites
Lee, C., Yang, W., & Parr, R. G. (1988) · Physical Review B · doi:10.1103/physrevb.37.785 · Cited by 100,874
Cited by
Main-Group Lewis Acids for C–F Bond Activation
Stahl, T., Klare, H. F. T., & Oestreich, M. (2013) · ACS Catalysis · doi:10.1021/cs4003244 · Cited by 470
Metadata
- Authors
- Panisch, R., Bolte, M., & Müller, T.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2006-07-12
- Volume
- 128
- Issue
- 30
- Pages
- 9676-9682
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W1974292995
- Cited by
- 270
- References
- 1
- FWCI
- 6.98
- Type
- journal article
- Language
- en
- Open access
- closed
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