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Amineborane-Based Chemical Hydrogen Storage: Enhanced Ammonia Borane Dehydrogenation in Ionic Liquids

Bluhm, Martin E., Bradley, Mark G., Butterick, Robert, Kusari, Upal, Sneddon, Larry G.·2006·Journal of the American Chemical Society

Abstract

Ionic liquids are shown to provide advantageous media for amineborane-based chemical hydrogen storage systems. Both the extent and rate of hydrogen release from ammonia borane dehydrogenation are significantly increased at 85, 90, and 95 degrees C when the reactions are carried out in 1-butyl-3-methylimidazolium chloride compared to analogous solid-state reactions. NMR studies in conjunction with DFT/GIAO chemical shift calculations indicate that both polyaminoborane and the diammoniate of diborane, [(NH3)2BH2+]BH4-, are initial products in the reactions.

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Metadata

Authors
Bluhm, M. E., Bradley, M. G., Butterick, R., Kusari, U., & Sneddon, L. G.
Venue
Journal of the American Chemical Society
Published
2006-05-28
Volume
128
Issue
24
Pages
7748-7749
ISSN
  • 0002-7863 (ISSN-L)
  • 1520-5126
OpenAlex
W2003235513
Cited by
613
References
0
FWCI
28.21
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Amineborane-Based Chemical Hydrogen Storage: Enhanced Ammonia Borane Dehydrogenation in Ionic Liquids. https://app.cochat.ai/papers/10.1021/ja062085v
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Bluhm, M. E., Bradley, M. G., Butterick, R., Kusari, U., & Sneddon, L. G. (2006). Amineborane-Based Chemical Hydrogen Storage: Enhanced Ammonia Borane Dehydrogenation in Ionic Liquids. Journal of the American Chemical Society. https://doi.org/10.1021/ja062085v

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.