The DOI matches its Crossref record.
15N−15N J-Coupling Across HgII: Direct Observation of HgII-Mediated T−T Base Pairs in a DNA Duplex
Abstract
N−N J -coupling across a metal center ( 2 J NN ) was clearly detected in a biological macromolecule (DNA duplex) for the first time. By using 2 J NN, the base pairing mode of mercury-mediated T−T pairs (T−Hg II −T) was definitely determined. This pairing mode was found to be a novel metal ion-binding mode for DNA and RNA molecules, in which imino proton−metal exchange processes are included. Accordingly, 2 J NN is highly important for the determination of the chemical structures of metal-mediated base pairs.
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Cited by
Li, J., Qi, Y., Yang, R., Chen, X., Chen, Z., & Zhu, J.-J. (2023) · Analytical Chemistry · doi:10.1021/acs.analchem.3c02851 · Cited by 11
Metadata
- Authors
- Tanaka, Y., Oda, S., Yamaguchi, H., Kondo, Y., Kojima, C., & Ono, A.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2006-12-21
- Volume
- 129
- Issue
- 2
- Pages
- 244-245
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2059331722
- Cited by
- 541
- References
- 0
- FWCI
- 7.86
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: 15N−15N J-Coupling Across HgII: Direct Observation of HgII-Mediated T−T Base Pairs in a DNA Duplex. https://app.cochat.ai/papers/10.1021/ja065552h
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- Tanaka, Y., Oda, S., Yamaguchi, H., Kondo, Y., Kojima, C., & Ono, A. (2007). 15N−15N J-Coupling Across HgII: Direct Observation of HgII-Mediated T−T Base Pairs in a DNA Duplex. Journal of the American Chemical Society. https://doi.org/10.1021/ja065552h
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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