The DOI matches its Crossref record.
3 nm-Scale Molecular Switching between Fluorescent Coordination Capsule and Nonfluorescent Cage
Abstract
A 3 nm-sized cage-shaped Hg 6 L 4 complex with large openings was quantitatively formed from trismonodentate ligand (L) and Hg 2+ ions in a self-assembled manner. The cage complex shows reversible interconversion with a capsule-shaped Hg 6 L 8 complex in response to the ratio of ligand to Hg 2+ . This structural switching is coupled with reversible ON/OFF switching of fluorescence between fluorescent Hg 6 L 8 capsule and nonfluorescent Hg 6 L 4 cage.
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Cited by
Challenges and breakthroughs in recent research on self-assembly
Ariga, K., Hill, J. P., Lee, M. V., Vinu, A., Charvet, R., & Acharya, S. (2008) · Science and Technology of Advanced Materials · doi:10.1088/1468-6996/9/1/014109 · Cited by 759
Xue, X., Wang, F., & Liu, X. (2008) · Journal of the American Chemical Society · doi:10.1021/ja076716c · Cited by 709
Recent Progress in Stimulus-Responsive Two-Dimensional Metal–Organic Frameworks
Li, C., Wang, K., Li, J., & Zhang, Q. (2020) · ACS Materials Letters · doi:10.1021/acsmaterialslett.0c00148 · Cited by 252
Metadata
- Authors
- Harano, K., Hiraoka, S., & Shionoya, M.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2007-04-06
- Volume
- 129
- Issue
- 17
- Pages
- 5300-5301
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W1977490135
- Cited by
- 168
- References
- 0
- FWCI
- 6.79
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: 3 nm-Scale Molecular Switching between Fluorescent Coordination Capsule and Nonfluorescent Cage. https://app.cochat.ai/papers/10.1021/ja0659727
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- Harano, K., Hiraoka, S., & Shionoya, M. (2007). 3 nm-Scale Molecular Switching between Fluorescent Coordination Capsule and Nonfluorescent Cage. Journal of the American Chemical Society. https://doi.org/10.1021/ja0659727
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
