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Low Temperature CO Oxidation over Unsupported Nanoporous Gold
Abstract
Supported Au nanoclusters are well-known for their unusual properties in catalysis. We describe here that nanostructured porous Au made via dealloying represents a new class of unsupported catalysts with extraordinary activities in important reactions such as CO oxidation. Although nanoporous Au may contain some oxides on the surface, our results demonstrate that it is metallic Au that plays the main role in this catalytic reaction. Furthermore, this material has good low-temperature catalytic stability and is extremely CO tolerant.
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Citations
Cited by
Generalized Fabrication of Nanoporous Metals (Au, Pd, Pt, Ag, and Cu) through Chemical Dealloying
Zhang, Z., Wang, Y., Qi, Z., Zhang, W., Qin, J., & Frenzel, J. (2009) · The Journal of Physical Chemistry C · doi:10.1021/jp811445a · Cited by 455
Shangguan, W., Liu, Q., Wang, Y., Sun, N., Liu, Y., Zhao, R., Li, Y., Wang, C., & Zhao, J. (2022) · Nature Communications · doi:10.1038/s41467-022-31474-2 · Cited by 332
Spiers Memorial Lecture : Role of perimeter interfaces in catalysis by gold nanoparticles
Haruta, M. (2011) · Faraday Discussions · doi:10.1039/c1fd00107h · Cited by 282
Du, R., Wang, J., Wang, Y., Hübner, R., Fan, X., Senkovska, I., Hu, Y., Kaskel, S., & Eychmüller, A. (2020) · Nature Communications · doi:10.1038/s41467-020-15391-w · Cited by 184
Engineering Self‐Supported Noble Metal Foams Toward Electrocatalysis and Beyond
Du, R., Jin, X., Hübner, R., Fan, X., Hu, Y., & Eychmüller, A. (2020) · Advanced Energy Materials · doi:10.1002/aenm.201901945 · Cited by 143
Metadata
- Authors
- Xu, C., Su, J., Xu, X., Liu, P., Zhao, H., Tian, F., & Ding, Y.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2006-12-15
- Volume
- 129
- Issue
- 1
- Pages
- 42-43
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2160746378
- Cited by
- 619
- References
- 0
- FWCI
- 18.45
- Type
- journal article
- Language
- en
- Open access
- closed
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- Xu, C., Su, J., Xu, X., Liu, P., Zhao, H., Tian, F., & Ding, Y. (2007). Low Temperature CO Oxidation over Unsupported Nanoporous Gold. Journal of the American Chemical Society. https://doi.org/10.1021/ja0675503
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.